Chemistry MCQs for NEET — Practice Questions with Answers

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Which of the following has the regular tetrahedral structure ?

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Explanation

The [BF₄]⁻ ion has a regular tetrahedral structure. Boron is surrounded by four fluorine atoms with no lone pairs on the boron atom, giving it a perfect tetrahedral shape. The other options do not have a regular tetrahedral geometry.

In $OF_2$ , number of bond pairs and lone pairs of electrons are respectively

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Bond strength increases with

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Explanation

Bond strength is directly related to bond order. Bond order refers to the number of chemical bonds between a pair of atoms. Higher bond order means more electrons are shared between the atoms, leading to a stronger bond. Therefore, bond strength increases with bond order.

$ O_2 ^ {2+ } $ will have

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In a molecule number of electrons in BMO are more as compared to ABMO, hence

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Explanation

In molecular orbital theory, if the number of electrons in bonding molecular orbitals (BMO) is greater than the number of electrons in anti-bonding molecular orbitals (ABMO), a bond will be formed. This is because the net stabilization energy is greater than the destabilization energy, leading to a stable bond.

The bond angle in the ammonium ion is equal to

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Explanation

The ammonium ion (NH₄⁺) has a tetrahedral geometry due to sp³ hybridization, which results in bond angles of approximately 109.28°.

The correct order of dipole moment is

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The correct order of the O – O bond length in $O_2 , H_2O_2 and O_3$ is

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Explanation

The bond length of a molecule is inversely proportional to the bond order. The bond orders for $O_2$, $H_2O_2$, and $O_3$ are 2, 1, and 1.5 respectively. Therefore, the bond length order is: $H_2O_2 extgreater O_3 extgreater O_2$.

Choose the incorrect statement.

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Explanation

A sigma (σ) bond is generally stronger than a pi (π) bond. The sigma bond is formed by the end-to-end overlap of atomic orbitals, which allows for a stronger overlap compared to the side-to-side overlap of the pi bond. Therefore, the statement 'σ bond is weaker than π bond' is incorrect.

Which of the following is not paramagnetic ?

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Explanation

$S^{2-}$ (sulfide ion) is not paramagnetic because it has no unpaired electrons. Paramagnetism arises due to the presence of unpaired electrons, which are absent in $S^{2-}$. Hence, $S^{2-}$ is diamagnetic.

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