Chemistry MCQs for NEET — Practice Questions with Answers

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What is 'resonance energy' or 'resonance stabilization energy'?

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Explanation

The context states: 'The energy of actual structure of the molecule (the resonance hybrid) is lower than that of any of the canonical structures. The difference in energy between the actual structure and the lowest energy resonance structure is called the resonance stabilisation energy or simply the resonance energy.'

Which of the following conditions is NOT necessarily true for canonical (resonance) structures?

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Explanation

The context states: 'The resonance structures have (i) the same positions of nuclei and (ii) the same number of unpaired electrons.' It also says: 'They contribute to the actual structure in proportion to their stability,' which implies they are not necessarily equally stable (some are more stable contributors than others). For example, in Problem 8.17, stability I > II > III is clearly mentioned.

In nitromethane ($\text{CH}_3\text{NO}_2$), the two N-O bonds are of the same length, intermediate between a N-O single bond and a N=O double bond. This indicates that nitromethane is:

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Explanation

The context states: 'however, it is known that the two N–O bonds of nitromethane are of the same length (intermediate between a N–O single bond and a N=O double bond). The actual structure of nitromethane is therefore a resonance hybrid of the two canonical forms I and II.'

What is the consequence of forming a resonance hybrid in terms of its energy compared to its canonical structures?

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Explanation

The context states: 'Resonance stabilizes the molecule as the energy of the resonance hybrid is less than the energy of any single canonical structure.'

A negative resonance effect (-R effect) is observed when:

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Explanation

The context states: 'This effect is observed when the transfer of electrons is towards the atom or substituent group attached to the conjugated system. For example in nitrobenzene this electron...'

Which of the following properties of transition metals primarily accounts for their catalytic activity?

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Explanation

The context states: 'The transition metals and their compounds are known for their catalytic activity. This activity is ascribed to their ability to adopt multiple oxidation states and to form complexes.'

In the Haber's Process for ammonia synthesis, which transition metal catalyst is employed?

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Explanation

The context mentions: 'finely divided iron (in Haber’s Process)' as an example of a transition metal catalyst.

The Contact Process for the manufacture of sulphuric acid utilizes which transition metal compound as a catalyst?

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Explanation

The context specifies: 'Vanadium(V) oxide (in Contact Process)' as a catalytic agent.

Which of the following statements is INCORRECT regarding interstitial compounds?

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Explanation

The context states: 'They have high melting points, higher than those of pure metals.' Therefore, the statement that they have lower melting points is incorrect.

What is the primary effect of bond formation between reactant molecules and atoms of a solid catalyst surface during catalysis?

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Explanation

The context explains: 'Catalysts at a solid surface involve the formation of bonds between reactant molecules and atoms of the surface of the catalyst... This has the effect of increasing the concentration of the reactants at the catalyst surface and also weakening of the bonds in the reacting molecules (the activation energy is lowering).'

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