Chemistry MCQs for NEET — Practice Questions with Answers

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Werner's experiments on cobalt(III) chloride compounds and ammonia showed that some compounds with identical empirical formulas, like $CoCl_3\cdot 4NH_3$, could have distinct properties (e.g., green vs. violet). What phenomenon did Werner use to explain this observation?

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Explanation

The NCERT states: 'Note that the last two compounds in Table 5.1 have identical empirical formula, $CoCl_3\cdot 4NH_3$, but distinct properties. Such compounds are termed as isomers.' Werner's theory provided a framework to understand such isomeric forms.

What was the primary experimental evidence that led Werner to propose two types of valencies?

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Explanation

The NCERT states, 'In a series of compounds of cobalt(III) chloride with ammonia, it was found that some of the chloride ions could be precipitated as AgCl on adding excess silver nitrate solution in cold but some remained in solution.' This observation was key to differentiating ionisable (primary) and non-ionisable (secondary) valences.

Which of the following methods is preferred for the preparation of pure alkyl halides from alcohols, particularly due to the escapable gaseous by-products?

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Explanation

The context states: 'Thionyl chloride is preferred because in this reaction alkyl halide is formed along with gases SO2 and HCl. The two gaseous products are escapable, hence, the reaction gives pure alkyl halides.'

Which of the following catalysts is required for the reaction of primary and secondary alcohols with HCl to form alkyl halides?

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Explanation

The context mentions: 'The reactions of primary and secondary alcohols with HCl require the presence of a catalyst, ZnCl2.'

Tertiary alcohols react with concentrated HCl to form alkyl halides under what conditions?

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Explanation

The context states: 'With tertiary alcohols, the reaction is conducted by simply shaking the alcohol with concentrated HCl at room temperature.'

What is the common name for the reaction where alkyl chlorides/bromides react with NaI in dry acetone to form alkyl iodides?

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Explanation

The context states: 'Alkyl iodides are often prepared by the reaction of alkyl chlorides/bromides with NaI in dry acetone. This reaction is known as Finkelstein reaction.'

Why is dry acetone used in the Finkelstein reaction?

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Explanation

The context explains: 'NaCl or NaBr thus formed is precipitated in dry acetone. It facilitates the forward reaction according to Le Chatelier’s Principle.'

Which of the following metallic fluorides is NOT mentioned in the context as being used in Swarts reaction for synthesizing alkyl fluorides?

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Explanation

The context lists: 'AgF, Hg2F2, CoF2 or SbF3' as metallic fluorides used in Swarts reaction. NaF is not mentioned.

Aryl chlorides and bromides are prepared by electrophilic substitution of arenes. What kind of catalyst is required for this reaction?

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Explanation

The context specifies: 'Aryl chlorides and bromides can be easily prepared by electrophilic substitution of arenes with chlorine and bromine respectively in the presence of Lewis acid catalysts like iron or iron(III) chloride.'

Why are fluoro compounds generally NOT prepared by electrophilic substitution of arenes with fluorine?

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Explanation

The context states: 'Fluoro compounds are not prepared by this method due to high reactivity of fluorine.'

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