When an ideal diatomic gas is heated at constant pressure, the fraction of the heat energy supplied which increases the internal energy of the gas, is -
Fraction of supplied energy which increases the internal energy is given by
For diatomic gas ⇒
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When an ideal diatomic gas is heated at constant pressure, the fraction of the heat energy supplied which increases the internal energy of the gas, is -
Fraction of supplied energy which increases the internal energy is given by
For diatomic gas ⇒
A monoatomic ideal gas, initially at temperature T1, is enclosed in a cylinder fitted with a frictionless piston. The gas is allowed to expand adiabatically to a temperature T2 by releasing the piston suddenly. If L1 and L2 are the lengths of the gas column before and after expansion respectively, then T1/ T2 is given by -
A mono atomic gas is supplied the heat Q very slowly keeping the pressure constant. The work done by the gas will be
⇒
∵ and for monatomic gas
A gas mixture consists of 2 moles of oxygen and 4 moles argon at temperature T. Neglecting all vibrational modes, the total internal energy of the system is
Oxygen is diatomic gas, hence its energy of two moles
Argon is a monoatomic gas, hence its internal energy of 4 moles
Total Internal energy = (6 + 5)RT = 11RT
An ideal gas expands isothermally from a volume V1 to V2 and then compressed to original volume V1 adiabatically. Initial pressure is P1 and final pressure is P3. The total work done is W. Then -
Work done by a system under isothermal change from a volume V1 to V2 for a gas which obeys Vander Waal's equation
According to given Vander Waal’s equation
Work done,
The molar heat capacity in a process of a diatomic gas if it does a work of when a heat of Q is supplied to it is -
or …..(i)
From first law of thermodynamics
.
Now molar heat capacity .
An insulator container contains 4 moles of an ideal diatomic gas at temperature T. Heat Q is supplied to this gas, due to which 2 moles of the gas are dissociated into atoms but temperature of the gas remains constant. Then
Q = ΔU = Uf – Ui = [internal energy of 4 moles of a monoatomic gas + internal energy of 2 moles of a diatomic gas] – [internal energy of 4 moles of a diatomic gas]
= RT
= RT
Note : (1) 2 moles of diatomic gas becomes 4 moles of a monoatomic gas when gas dissociated into atoms.
Internal energy of μ moles of an ideal gas of degrees of freedom F is given by
f = 3 for a monoatomic gas and 5 for diatomic gas.
The volume of air increases by 5% in its adiabatic expansion. The percentage decrease in its pressure will be -
or
or or
= –1.4 × 5 = 7%
The temperature of a hypothetical gas increases to times when compressed adiabatically to half the volume. Its equation can be written as
= constant
∴ or
∴ or
∴ PV3/2 = constant
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