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One mole of ideal monoatomic gas γ=5/3 is mixed with one mole of diatomic gas γ=7/5. What is γ for the mixture? γ denotes the ratio of specific heat at constant pressure, to that at constant volume

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Explanation

1.

       γmix=μ1γ1γ1-1+μ2γ2γ2-1μ1γ1-1+μ2γ2-1=1×5353-1+1×7575-1153-1+175-1=32=1.5

A gaseous mixture contains equal number of hydrogen and nitrogen molecules. Specific heat measurements on this mixture at temperatures below 100 K would indicate that the value of γ (ratio of specific heats) for this mixture is

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Explanation

3. Below 100 K only translational degree of freedom is considered. Hence 

       γmixture = μ1Cp,1 + μ2Cp,2 μ1Cv,1 + μ2Cv,2 where μ1 and μ2 are moles of samples A and Bγmixture=μ1γ1γ1-1+μ2γ2γ2-1μ1γ1-1+μ2γ2-1 

according to question, 

       μ1=μ2  and  γ1=γ2   =1+23=53

        γmix=γ1=53

 

One mole of monoatomic gas and three moles of diatomic gas are put together in a container. The molar specific heat in J K-1 mol-1 at constant volume is R=8.3 J K-1 mol-1

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Explanation

1.    CVmix=μ1CV1+μ2CV2μ1+μ2                  =1×32R+3×52R1+3                  =94R=94×8.3  =18.7

The number of translational degrees of freedom for a diatomic gas is

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Explanation

2. Number of translational degrees of freedom (3) are same for all types of gases.

For a gas if ratio of specific heats at constant pressure and volume is γ then value of degrees of freedom is

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Explanation

2.   γ=1+2f ,        γ-1=2f        f2=1γ-1         f=2γ-1

If a gas has n degrees of freedom ratio of specific heats of gas is

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Explanation

4.    γ=CPCV=f2R+Rf2R =1+2f =1+2n

A gaseous mixture consists of 16g of helium and 16g of oxygen. The ratio CPCV of the mixture is

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Explanation

4.      μ1=moles of helium =164=4      μ2=moles of oxygen =1632=12                4×5/353-1+1/2×7/575-1453-1+1/275-1=1.62

The pressure exerted by the gas on the walls of the container because

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Explanation

3. Pressure, P=FA=1A.pt        p=Change in momentum

Gas at a pressure P0 is contained in a vessel. If the masses of all the molecules are halved and their speeds are doubled, the resulting pressure P will be equal to

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Explanation

2.    vrms=3Pρ=3PVm         vrmsPM         v1v2=P1P2×m2m1        v2v=P0P2×m/2m         P2=2P0

A box contains n molecules of a gas. How will the pressure of the gas be effected, if the number of molecules is made 2n?

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Explanation

(c)

     PV=nRTn=Molecules×NA  P2P1=N2N1=21       P2=2P1

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