In the spectrum of hydrogen. the ratio of the longest wavelength in the Lyman series to the longest wavelength in the Balmer series is:-
In hydrogen atom, wavelength of characteristic spectrum
=Rz2 [1/n12-1/n22]
For Lyman series n1=1 , n2=2
…(i)
For Balmer series n1=2, n2=3
… (ii)
Dividing Eq. (ii) by Eq. (i) we get
=5/36 x 4/3 =5/27