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In the spectrum of hydrogen. the ratio of the longest wavelength in the Lyman series to the longest wavelength in the Balmer series is:-

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Explanation

In hydrogen atom, wavelength of characteristic spectrum

1λ=Rz2 [1/n12-1/n22]

For Lyman series n1=1 , n2=2

1λ1= =Rz2[1/(1)2-1/(2)2] …(i)

For Balmer series n1=2, n2=3

1λ2==Rz2 [1/(2)2-1(3)2] … (ii)

Dividing Eq. (ii) by Eq. (i) we get

λ1λ2=5/36 x 4/3 =5/27

Hydrogen atom in ground state is excited by a monochromatic radiation of λ=975Å. The number of spectral lines in the resulting spectrum emitted will be:

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Explanation

(c)

Energy provided to the ground state electron:E=hcλ=6.63×10-34×3×108975×10-10=12.75eVIt means the electron jumps to 3rd excited state ( n=4)No. of spectral lines=nn-12=6

Ratio of longest wavelengths corresponding to Lyman and Balmer series in twinge!) spectrum ts

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Explanation

(a) Wavelength for Lyman series 

λL=1/R(1-1/4)=4/3R

and wavelength for Balmer series

λB=1/R(1/4-1/9)=1/R(5/36)=36/5R

   λLB=4/3R x 5R/36=5/27

       =>λLB=5:27  

Electron in hydrogen atom first jumps from third exicted state to second exicted state and then from second exicted to the first excited state. The ratio of the wavelengths λ1:λ2 emitted in the two cases is

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Explanation

Here, for wavelength λ1

n1=4 and n2=3

and for λ2, n1=3 and n2=2 

We have hcλ=-13.61n22-1n12

So, for λ1

       hcλ1=-13.6142-132

         hcλ1=13.67144                                ...(i)

Similarly, for λ2

       hcλ2=-13.6132-122

         hcλ2=13.6536                    ...(ii)

Hence, from Eqs. (i) and (ii), we get 

                     λ1λ2=207

An electron of a stationary hydrogen atom passes from the fifth energy level to the ground level. The velocity that the atom acquired as a result of photon emission will be

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Explanation

1λ=R1n12-1n22 Here n1=1 and n2=5Hence 1λ=R112-152 =2425RNow photon energy-E=hcλ=2425hcRHere the momentum of photon=momentum of atomThus P=Ec=2425hRVelocity of atom v=Pm=24hR25m

Monochromatic radiation emitted when electron on hydrogen atom jumps from first excited to the ground state irradiates a photosensitive material. The stopping potential is measured to be 3.57 V.The threshold frequency of the material is:

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Explanation

Energy released from emission of electron

           E=-3.4--13.6

              =10.2 eV

From photo electric equation.

Work function

   ϕ=E-eV=hv

   v=E-eVh

     =10.2-3.57e6.67×10-34

v=6.63×1.6×10-196.67×10-34

=1.6×1015Hz

 

The transition from the state n=3 to n=1

a hydrogen like atom results in ultraviolet

radiation. Infrared radiation will be obtained

in the transition from

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Explanation

 

Infrared radiation is found in Paschan, Brackett

and pfund series and it is obtain when electron

transition occur from high energy level to 

minimum third level.

The wavelength of the first line of Lyman series for hydrogen atom is equal to that of the second line of Balmer series for a hydrogen-like ion. The atomic number Z of hydrogen-like ion is 

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Explanation

Lyman series for H-ion

                    hcλ=Rhc112-122

and for H-like ion 

                     hcλ=Z2Rhc122-142

112-122=Z214-116          1-14=Z214-116                      Z=2

The energy of a hydrogen atom in the ground state is -13.6 eV. The energy of a He+ ion in the first excited state will be 

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Explanation

Energy E of an atom with principal quantum number n is given by E=-13.6n2Z2 for first excited state n=2 and for He+ Z=2

           E=-13.6×2222

               =-13.6 eV

An alpha nucleus of energy 12mv2 bombards a heavy nuclear target of charge Ze. Then the distance of closest approach for the alpha nucleus will be proportional to

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Explanation

αparticle of mass m possesses initial velocity v, when it is at a large distance from the nucleus of an atom having atomic number Z. At the distance of closest approach, the kinetic energy of αparticle is completely converted into potential energy. Mathematically,

            12mv2=14πε02eZer0

           r0=14πε02Ze212mv2

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