Assuming fully decomposed, the volume of CO2 released at STP on heating 9.85g of BaCO3 [at. mass of Ba = 137] will be
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The total number of valence electrons in 4.2g of ion is (NA is the Avogadro's number)
(c) Moles of ion = 4.2/42=0.1
Each nitrogen atom has 5 valence electrons. Therefore, total number of electrons of ion=16
Total number of electrons in 0.1 mole or
4.2g of ion= 0.1x16xNA
=1.6NA
In Haber process 30L of dihydrogen and 30L of dinitrogen were taken for reaction which yielded only 50% of the expected product. What will be the composition of gasesous mixture under the a fore said condition in the end?
As only 50% of the expected product is formed, hence only 10L of NH3 is formed.
Thus, for the production of 10L of NH3 , 5L of N2 and 15L of H2 are used and composition of gaseous mixture under the a fore said condition in the end is
H2 = 30-15=15L
N2 = 30-5=25L
NH3 =10L
The number of atoms in 4.25 g of NH3 is approximately
(D) Weight of NH3 = 4.25g
Number of moles of NH3 = =0.25 mol
Number of molecules in 0.25 mole of NH3 = 0.25 x 6.023 x 1023
So, number of atoms = 4 x 0.25 x 6.023 x 1023
=6.0 x 1023
In the reaction, 4NH3(g)+ 5O2(g) 4NO(g) +6H2O(l)
When 1 mole of ammonia and 1 mole of O2 are made to react to completion, then
(c) 4NH3(g)+ 5O2(g) 4NO(g) +6H2O(l)
4mol 5 mol 4mol 6mol
According to the equation,
5 moles of O2 required = 4 moles of NH3
1 mole of O2 required =4/5= 0.8 moles of NH3
While 1mole of NH3 requires = 5/4=1.25 moles of O2
As there is 1 mole of NH3 and 1 mole of O2 , so all the oxygen will be consumed.
An element, X has the following isotopic composition:
200X : 90%, 199X : 8.0%, 202X : 2.0%
The weighted average atomic mass of the naturally occurring element X is closest to
(d) Weight of 200X = 0.90 x 200 = 180.00 u
Weight of 199X =0.08 x 199=15.92 u
Weight of 202X = 0.02 x 202=4.04 u
Total weight = 199.96 = 200u
The hydrated salt Na2SO4.nH2O, undergoes 55% loss in mass on heating and becomes anhydrous. The value of n will be:
Na2SO4.10H2O
12 g of Mg (atomic mass=24) will react completely with an acid to give:
(b) Mg + 2HCl MgCl2 + H2
Therefore,
12g Mg gives 1/2 mole of H2
The molality of 15% (w/vol.) solution of H2SO4 of density 1.1g/cm3 is approximately:
(d) m = =1.6
H3PO4 is a tribasic acid and one of its salts is NaH2PO4. What volume of 1 M NaOH should be added to 12g NaH2PO4 (Molar mass 120) to exactly convert it into Na3PO4?
(c) Meq. of NaH2PO4 =Meq. of NaOH;
Thus, 12/120/2*1000 = 1 x V
V = 200 mL
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