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What volume of HCl solution of density 1.2 g/cm3 and containing 36.5% by weight HCl, must be allowed to react with zinc(Zn) in order to liberate 4.0 g of hydrogen?

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Explanation

Zn+2HCl  ZnCl2+H2;moles of H2 evolved = 2 Moles of HCl required = 4 V×1.2×0.36536.5=4;      V=333.33 mL

What is the molar mass of diacidic organic Lewis base (B), if 12 g of chloroplatinate salt BH2PtCl6 on ignition produced 5 gm residue of Pt?

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Explanation

B H2PtCl6  Pt;  12MB+410=5195=moles of Pt;    Molecular mass of base = 58

Equivalent weight of FeS2 in the half reaction, FeS2  Fe2O3+SO2 is:

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Explanation

n=1+5×2

The equivalent weight of HCl in the given reaction is: K2Cr2O7+14HCl  2KCl+2CrCl3+3Cl2+H2O

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Explanation

14 mole HCl- loses 6 mole e-;    1 mole HCl loses 614 mole e-     eq. wt. of HCl = M614     36.5×146=85.1

What volume of O2g measured at 1 atm and 273 K will be formed by action of 100 mL of 0.5 N KMnO4 on hydrogen peroxide in an acid solution? The skeleton equation for the reaction is
KMnO4+H2SO4+H2O2 K2SO4+MnSO4+O2+H2O

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Explanation

50 meq. KMnO4=10 mmole KMnO4or  25 mmole of O2=25×22.4×10-3                                     = 0.56 L

5H2O+ 3H2SO+ 2KMnO4 = 5O+ 8H2O + 2MnSO4 + K2SO4

A solution of Na2S2O3 is standardized iodometrically against 0.167 g of KBrO3. This process requires 50 mL of the Na2S2O3 solution. What is the normality of the Na2S2O3?

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Explanation

Eq. wt. of KBrO3=16 of its mol. wt.                              =16×167NNa2S2O3=0.167167×6×10.05=0.12 N

The NH3 evolved due to complete conversion of N from 1.12 g sample of protein was absorbed in 45 mL of 0.4 N HNO3. The excess acid required 20 mL of 0.1 N NaOH. The % N in the sample is:

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Explanation

milliequivalent of NH3 reacted with HNO3  =45×0.4-20×0.1=16     W17×1000=16;              WNH3=0.272 g;wt. of N=0.272×1417=0.224%N in the sample =0.2241.12×100=20%

Cisplatin, an anticancer drug, has the molecular formula PtNH32 Cl2. What is the mass (in gram) of one molecule? (Atomic weights : Pt=195, H=1.0, N=14, Cl=35.5)

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Explanation

The molecular weight of cisplatin is 300 g/mol (195 g/mol for Pt + 2 × 14 g/mol for N + 6 × 1 g/mol for H + 2 × 35.5 g/mol for Cl). Converting to grams per molecule using Avogadro's number (6.022 × 10^23 molecules/mol), we get 4.98 × 10^-22 g/molecule.

The conversion of oxygen to ozone occurs to the extent of 15% only. The mass of ozone that can be prepared from 67.2 L oxygen at 1 atm and 273 K will be:

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Explanation

Mole of O2= 67.222.4=3 mole3O22O3 Mole of Ozone formed= 23×15100×3                                              = 0.3 mole Mass of Ozone formed= 0.3×48 g = 14.4 g

A silver coin weighing 11.34 g was dissolved in nitric acid. When sodium chloride was added to the solution all the silver (present as AgNO3) was precipitated as silver chloride. The weight of the precipitated silver chloride was 14.35 g. Calculate the percentage of silver in the coin.

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Explanation

Ag + HNO3AgNO3AgNO3 + NaClNaNO3 + AgClPOAC on AgMole of Ag in coin = mole of Ag in AgCl               a=14.35143.5=0.1 moleMass of Ag in coin = 0.1×108=10.8 g %silver in coin= 10.811.34×100%  =95.2%

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