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Which set contains only covalently bonded molecules?

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Explanation

(a)  The set of compound BCl3 , SiCl4 , PCl3 are predominately covalent compounds . NH4Br and NaI ionic compounds and Al contains metalic lattice. 

In which of the following species, d-orbitals having xz and yz two nodal planes involved in hybridization of central atom?

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Explanation

(c) IO2F2-: Hyb. sp3d, [spxpypzdz2]CIF4-: Hyb. sp3d2, [spxpypzdx2-y2dz2]IF7: Hyb. sp3d3. [spxpypzdx2-y2dxydz2] dxy: orbitals has two nodal planes xz and yz

Select pair of compound in which both have differant hybridization but have same molecular geomatery:

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Explanation

(b)        BF3         sp2       Trigonal planar

           BrF3      sp3d      Bent 'T' shape

          ICI2         sp3d      Linear

          BeCI2         sp       Linear

         BCI3          sp2       Trigonal planar

          PCI3          sp3      Pyramidal

         NCI3        sp3        Pyramidal

Which molecule does not exist?

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Explanation

(b) Maximum covalency of oxygen atom is three, hence OF4 does not exist

A compound contains three elements A, B and C , if the oxidation of A = +2, B = +5 Aand C = -2, the possible formula of the compound is:

 

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Explanation

(b) A2++BC43-A3(BC4)2

The spacies having no pπ-pπ bond but has bond order equal to that of O2

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Which pair of atom form strongest ionic bond?

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Explanation

(d) Among given non-metals , O-atom has high electron affinity and strong ionic bond is formed between Al and O-atom

The correct order of increasing s-character (in percentage) in the hybrid orbitals of the following molecules/ions is:

(i) CO32-           (ii) XeF4                (iii) I3                     (iv) NCI3                         (v) BeCl2

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Explanation

(a) CO3-          XeF4            I3-                    NCL3                      BeCL2 sp2         sp3d2         sp3d                  sp3                            sp

How many resonance forms can be written for the nitrate ion, (NO3-)?

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Explanation

The nitrate ion (NO₃⁻) has three resonance structures due to the delocalization of the negative charge over the three oxygen atoms. The three resonance forms help stabilize the ion by distributing the negative charge evenly.

Which of the following fact is directly explained by the statement 'oxygen is a simillar atom than sulpher'?

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Explanation

(d) As size of sulphur is higher than that of oxygen atom, hence bond length of SH bond is higher than of  OH bond.

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