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In which of the following compounds octet is complete and incomplete for all atoms:

                 Al2Cl6      Al2CH36       AlF3      Dimer of BeCl2     Dimer of BeH2                               

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Explanation

In Al2Cl6, Al has an incomplete octet. In Al2(CH3)6, both Al and C have complete octets. In AlF3, Al has an incomplete octet, while F has a complete octet. In the dimer of BeCl2, Be has a complete octet, while Cl has an incomplete octet. In the dimer of BeH2, both Be and H have incomplete octets.

In which of the following metal of metal bond is present?

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Explanation

(c)    ClHgHgCl

    Mercurousion is represent as Hg22+ it is evidenced by the fact that its  μ=0, i.e., it is diamagnetic. it is possible only when there is presence of a metal-matal bond.

The pair of elemnts which on combination are most likely to form an ionic compound is : 

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Explanation

(b) KO2 is an ionic compound

The species showing pπ-dπ  overlapping is :

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Explanation

(b) only P has d-orbitals. 

Which of the following interaction lies in the range of 8 -  42 kJ/mol?

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Explanation

(d) (a)  H2....H2O               Dipole-induced dipole interaction (van der Waal's force) energy<8kJ/mol

(b) HCl.....HCI         Dipole-dipole interaction (van der Waal's force)<8kJ/mol

(c) H20.....HF                      H-bond 

(d) all                

 

 

 

The number of antibonding electrons pairs in O22- on the basis of MO theory are:

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If CdI2 is pink in colour, the CdCl2 will be '.............' coloured.

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Explanation

(d) In CDI2, Pink colour is due to polarization of I- by Cd2+ has pseudo noble gas configuration. In CdCI2, extent of polarization of Cl- by Cd2+ is relatively less, hence specific colour cannot be predicted.

Which are true statements among the following?

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Explanation

(b)I3 + has a bent shape which is sp3 hybridized. The central atom iodine atom has 6 electrons because of one positive charge, it will make single bonds with 2 I atoms to complete their and it`s own octet, keeping the loan pair upside we get a bent shape.

In which molecule all atoms are coplanar?

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Explanation

(b) Due to sp2- hybridization.

Which species does not exist?

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Explanation

(c) Carbon cannot accept 6Cl-, since it has no vacant d-orbitals. 

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