NEET Practice Questions (MCQs) with Answers & Solutions

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The average kinetic energy of two moles of CO2 at a certain temperature is 1800 cal. The temperature of the gas is-

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Explanation

(A).  The average kinetic energy of molecule is given by 32RTN where RN is Boltzmann constant.

For a real gas, PV is a constant over a small range of pressures, at

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Explanation

(A). This is referred as Boyle’s temperature.

A vessel of volume 0.02 m3 contains a mixture of hydrogen and helium at 20°C and 2 atm pressure. The mass of mixture is 5 gms. Find the ratio of mass of hydrogen to that of helium in the mixture (At. wt. He = 4)

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Explanation

A.   n=2×20293×0.0821=1.67=53            x2+5-x4=53    15+3x=20     so x=53           Required ratio=x5-x=5/35-5/3=12

Four particles have velocities 1, 0, 2, 3 m/s. The root mean square of the particles is (in m/s)

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Explanation

(B).  Vrms=12+02+22+324=3.5

Joule-Thomson expansion of an ideal gas is an

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Explanation

(C). Joule-Thomson effect occurs at constant enthalpy.

The pressure-volume plot for an ideal gas at a given temperature has the form of a

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The average, RMS and most probable velocities of gas molecules at STP increase in the order

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Explanation

(B). Molecular speed of gases are of velocity

       (1) The RMS root mean square velocity

             C =3RTM

        (2) Average velocity = 8RTπM

             RMS=1.085 × Average velocity

         (3) Most probable velocity = 2RTM

        The ratio is

         Most probable velocity : Average velocity : RMS

         =2 : 8π : 3=1 : 1.128 : 1.224

Equal volumes of SO2 and He at a temperature T and pressure P are allowed to effuse through a hole. The rate of effusion of helium is

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Explanation

(B). The relative rates of diffusion of gases with respect to molecular weights is given by the expression

                r1r2=M2M1=4 ; M2=64 and M1=4

Flask X is filled with 20g of CH4 gas at 100°C and another identical flask Y with 40g O2 gas at the same temperature. Which one of the following statements is correct – [Molar masses g mol-1 CH4 = 16.0, O2 = 32.0]

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Explanation

A.      nCH4=2016=54             nO2=4032=54             nCH4=nO2         hence pressure is equal

A certain volume of argon gas (Mol. wt. = 40) requires 45 s to effuse through a hole at a certain pressure and temperature. The same volume of another gas of unknown molecular weight requires 60s to pass through the same hole under the same conditions of temperature and pressure. The molecular weight of the gas is

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Explanation

(C).  This based on Graham's law of Diffusion.

        r1r2=M2M1

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