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The heat of neutralisation of HCl by NaOH is -55.9 kJ/mole. If the heat of neutralisation of HCN by NaOH is -12.1 kJ/mole, then energy of dissociation of HCN is-

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Explanation

The heat of neutralisation = -55.9 kJ

 The heat of neutralisation of HCN by NaOH = the heat of neutralisation + the energy of dissociation of HCN

= -12.1 kJ

or the energy of dissociation of HCN

= +55.9-12.1 = 43.8 kJ

For a reaction at equilibrium-

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Explanation

For a reaction at equilibrium G=0 and not G.

Using only the following data:

(I) Fe2O3s+3COg2Fe(s)+3CO2(g);H=-26.8 kJ

(II) Fes+COgFeOs+COg;H=+16.5 kJ

the H value, in kilojoules, for the reaction

Fe2O3s+COg2FeOs+CO2g is calculated to be:

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Explanation

from equation (I) + (2×II) ;     H= 6.2 kJ

82 litres of carbon dioxide are produced at a pressure of 1 atm by the action of acid on a metal carbonate. The work done by the gas (in calories) in pushing back the atmosphere is (R = 0.082 litre-atm deg-1mol-1)

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Explanation

The work done by a gas is given by

W= PV

Among the following, the reaction for which H=E is-

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Explanation

When n=0, H=E  because H=E+RT n.

For which change HE

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Explanation

H=E+nRT

Enthalpy change when 1.00 g water is frozen at 0C, is :

Hfus=-1.435 kcal mol-1

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Explanation

H(per g) = -1.43518 kcal =  - 0.0797 kcal g

One mole of hydrogen gas at 25C and 1 atm pressure is heated at constant pressure until its volume has doubled. Given that Cv for hydrogen is 3.0 cal deg-1 mol-1, the H and E for this process are-

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Explanation

H=CPT and E=CVT.

CP-CV=R using these equations after calculating the final temperature, the desired result is obtained.

The enthalpy change of the reaction

Al2Cl6s+6Nas2Als+6NaCls is -257 kcal.

Given the heat of formation of NaCl(s) is 98.0 kcal, the heat of formation of Al2Cl6s is-

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Explanation

H of reaction = HNaCl ×6-HAl2Cl6 where HNaCl and HAl2Cl6 are the heats of formation of NaCl and Al2Cl6.

Some of the thermodynamic parameters are state variables while some are process variables. Some grouping of the parameters are given. Choose the correct one-

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Explanation

Internal energy and volume depend upon states.

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