The equilibrium, 2SO2 (g) + O2 (g) 2SO3 (g)
shifts forward if:
(b) Follow Le-Chatlelier's principle.
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The equilibrium, 2SO2 (g) + O2 (g) 2SO3 (g)
shifts forward if:
(b) Follow Le-Chatlelier's principle.
The pH of blood is maintained by CO2 by and H2CO3 in the body and chemical constituents of blood. This phenomenon is called:
(b) A buffer of H2CO3 and is formed.
Which of the following statements about pH and H+ ion concentration is correct ?
(b) CH3COOH is weak acid while NaOH is strong base, so one equivalent of CH3COOH. Hence, one equivalent of each does not have pH value 7. As the NaOH is a strong base, the solution will be basic having a pH more than 7.
At temperature T, a compound AB2 (g) dissociates according to the reaction 2AB22AB(g) +B2(g) with a degree of dissociation x, which is small compared with unity. The expression for Kp, in terms of x and the total pressure P , is:
(a) 2AB22AB(g) +B2(g)
1 0 0
1-x x x/2
... Kp =
x being small ... 1-x 1 and 1+ x/2 1
... Kp = x3.P/2
The rate constants for forward and backward reaction of hydrolysis is ester are 1.1 x10-2 and 1.5x10-3 per minute. Equilibrium constant for the reaction,
CH3COOC2H5 + H+ CH3COOH + C2H5OH is
(d) Equilibrium constant, K=kf/kb
= Forward rate constant/ Backward rate constant
= 1.1x10-2/1.5x10-3
= 11/1.5 = 7.33
What happens to pH of a solution when NH4Cl crystal is added to a dilute solution of NH4OH?
(a) Due to common ion effect, dissociation of NH4OH decreases and thus, pOH increases or pH decreases.
For the reactions,
A B; Kc = 2
B C; Kc = 4
C D; Kc = 6
Kc for the reaction, A D is:
(d) 2=[B]/[A]; 4=[C]/[B] and 6=[D]/[C]
Thus, on multiplying
2x4x6 = [D]/[A], i.e, Kc for the reaction.
The phenomenon of interaction of anions and cations furnished by an electrolyte with the H+ and OH- ions of water to produce acidic nature or alkalinity is known as hydrolysis. In hydrolysis:
(d) These are characteristics of salt hydrolysis.
For the reaction equilibrium,
2NOBr(g) 2NO(g) + Br2, if = P/9 at equilibrium and P is total pressure. The ratio of Kp/P is equal to:
The equilibrium constant Kp for the reaction 2NOBr(g) ⇌ 2NO(g) + Br2 is given by Kp = [NO]2[Br2]/[NOBr]2. At equilibrium, PBr2 = P/9, where P is the total pressure. Since there are 3 moles of gas on the product side and 2 moles on the reactant side, Kp/P = (P/9)/(P(2/3))2 = 1/81.
In the system, CaF2(s) Ca2+ (aq) + 2F-(aq), increasing the concentration of Ca2+ ions 4 times will cause the equilibrium concentration of F- ions to change to:
(b) Kc = [Ca2+][F-]2 ;
if [Ca2+] = 4x[Ca2+];
To have Kc constant [F-] should be [F-]/2.
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