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Which of the following statement regarding H2O2 is wrong.

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Explanation

(C).  H2O2 is a polar compound and its dipole moment is not zero. It is stable in acid medium

        because its decomposition can be retarded by adding small amounts of acid. It also acts as

        oxidising and reducing agent. Pure H2O2 is slightly acidic, because its aqueous solution is

        slightly or weakly acidic.

Polyphosphates are used as water softening agents because they –

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Explanation

(C).  Sodium hexametaphosphate-a polyphosphate, combines with cations i.e., Ca2+, Mg2+ to

        form soluble complexes.

            2Ca2++Na2Na4PO364Na++Na2Ca2PO36                                                              complex soluble

Which of the following is correct for hydrogen –

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Explanation

(A).  Hydrogen form bonds in +1 and –1 oxidation state.

Permanent hardness of water can be removed, by adding –

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Explanation

(C).  Washing soda removes both the temporary and permanent hardness by converting soluble

        calcium and magnesium compounds into insoluble carbonates. 

                     CaCl2+Na2CO3          CaCO3+2NaCl             CaSO4+Na2CO3            CaCO3+Na2SO4             CaHCO32+Na2CO3            CaCO3+2NaHCO3

At absolute zero.

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Explanation

(A).  The % of para form increases if the temperature is lowered and at absolute zero only para

        form having lowest internal energy exists.

 

Ordinary dihydrogen is an equilibrium mixture of ortho and para hydrogen.

ortho hydrogen↽⇀para hydrogenortho hydrogen↽⇀para hydrogen

The amount of ortho and para hydrogen varies with temperature as:

  • At 0°K, hydrogen contains mainly para hydrogen which is more stable.
  • At the temperature of liquefaction of air, the ratio of ortho and para hydrogen is 1 : 1.
  • At the room temperature, the ratio of ortho to para hydrogen is 3 : 1.
  • Even at very high temperatures, the ratio of ortho to para hydrogen can never be more than 3 : 1.

Thus, it has been possible to get pure para hydrogen by cooling ordinary hydrogen gas to a very low temperature (close to 20 K) but it is never possible to get a sample of hydrogen containing more than 75% of ortho hydrogen.

Metal which does not react with cold water but evolves H2 with steam is –

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Explanation

(D).   Iron (Fe) does not react with cold water to give H2. However, iron reacts with steam to give H2.

Hardness of water is due to presence of salts of –

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Explanation

(B).   Hardness of water is due to the presence of bicarbonates, chlorides and sulphates of Ca and

         Mg on it. These Ca2+ and Mg2+ ions react with the anions of fatty acids present in soaps to

         form curdy white precipitates. As a result, hard water does not produce lather with soap

         immediately. 

The melting points of most of the solid substances increase with an increase of pressure acting on them. However ice melts at a temperature lower than its usual melting point when the pressure is increased. This is because.

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Explanation

(A).  Because ice is less denser than water.

An ionic compound is dissolved simultaneously in heavy water and ordinary water, its solubility is –

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Explanation

(B).   Solubility of ionic compounds is less in heavy water.

In lab H2O2 is prepared by -

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Explanation

(A).  H2SO4+BaO2            BaSO4+H2O2

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