NaOH is prepared by the electrolysis of:
(a)
When aquous sodium chloride undergo electrolysis in presence of platinum electrodes, the reaction is follows-
NaCl ---> Na+ + Cl-
H20 ---> H+ + OH-
At anode, Cl- ions are discharged in preference to OH- ions.
Cl- ---> (1/2)Cl2 + e-
At cathode, H+ ions are discharged in preference to Na+ ions.
H+ + e- ---> (1/2)H2
Overall reaction is -
NaCl + H20 ---> Na+ + OH- + (1/2)H2 + (1/2)Cl2