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Which of the following is not a greenhouse gas :-

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Explanation

(1)

Hydrogen is not a greenhouse gasGreenhouse gases must contain different atoms that are able to vibrate in a specific pattern to absorb heat energy

The concentration of Peroxy Acetyl Nitrate (PAN) maximum in:-

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Explanation

Levels of peroxyacetyl nitrate and total oxidant at Riverside, Calif., November 13, 1967. Maximum concentration (58 ppb) of PAN measured to date occurred between 6:30 and 8:00 p.m. Total oxidant was above ad- verse level but did not reach an unusually high level for a "smoggy" day.

This is called photochemical smog...

If NaCl is doped with 10-4 mol % of SrCl2, the concentration of cation vacancies will be (NA = 6.023 x 1023 mol-1)                                                                             

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Explanation

(c) Doping of NaCl with 10-4 mol % of SrCl2 means, 100 moles of NaCl are doped with 10-4  mol of SrCl2.

... 1 mol of NaCl is doped with

                      SrCl2 = 10-4/100 = 10-6 mole

 As each Sr2+ ion introduces one cation vacancy.

... Concentration of cation vacancies

                             = 10-6 mol/mol of NaCl

                             = 10-6 x 6.023 x 1023 mol-1

                             = 6.023 x 1017 mol-1

                      

CsCl crystallises in body-centred cubic lattice. If 'a' is its edge length then which of the following expressions is correct?

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Explanation

(C) For bcc if edge length is a, then 

rCs+ + rCl- = (3/2)*a

Metals have conductivity of the order of (ohm-1 cm-1):-

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Explanation

(b) The conductance order of metals is 106 to 108 ohm-1 cm-1.

Total volume of atoms present in a face centred cubic unit cell of a metal is ( r is atomic radius):

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Explanation

(D) Volume of atoms in cell = 4/3 πr3 x n (n =4 for fcc)

=  4/3 x πr3 x 4 = 16/3 πr3

Which is covalent solid?

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Explanation

(d) All are covalent molecules. A covalent solid has atoms as constituent units at lattice points held together by covalent bonds.

The mass of a unit cell of CsCl corresponds to:-

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Explanation

(c) A unit cell of CsCl having bcc structure consists of 8 atoms at the corner and one atom at centre.

Thus, no. of Cl- = 8x1/8 =1 and no. of Cs+ =1x1=1

Thus, no. of CsCl unit per unit cell = 1

The intermetallic compound LiAg has a cubic crystalline structure in which each Li atom has 8 nearest neighbour silver atoms and vice-versa. What is the type of unit cell?

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Explanation

(a) The bcc structure has co-ordination no. of eight.

How many unit cells are present in a cube shaped ideal crystal of NaCl of mass 1.00g?

[ Atomic masses Na=23, Cl = 35.5]

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Explanation

(a) Mass of one unit cell = V x d (V is volume, d is density) 

= a3 x d

Also, density = (n x at. mass) /(a3 x av.no.)

Mass of one unit cell = (a3 x n x at.mass) / (a3 x av.no.) = (n x at. mass )/(av.no.)

= 4x58.5 / 6.02 x 1023 (n=4 for cubic shape)

=38.87 x 10-23g

No. of unit cell in 1g = 1/38.87x10-23 = 2.57 x 1021

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