NEET Practice Questions (MCQs) with Answers & Solutions

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The hybridisation of atomic orbitals of nitrogen in NO2+,NO3- and NH4+ are 

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Explanation

No. of hybrid orbitals = Total no. of sigma bonds +lone pair of electrons. The no. of sigma bonds in NO2+,NO3- and NH4+ are 2,3 and 4 respectively. So the hybridisation is sp, sp2 and sp3 respectively.

Which of the following hybrides is most acidic

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Explanation

Due to weak bond H2Te can furnish hydrogen more readily.The increasing order of acidic nature is

H2O < H2S < H2Se < H2Te

Which of the following is incorrect about H2SO4

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Explanation

H2SO4 cannot act as reducing agent, because when a substance acts as reducing agent, it is oxidised itself and there is increase in O.N. In H2SOthe O.N. of sulphur is +6,which is maximum.

Which of the following oxide is most acidic

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Explanation

The acidity decrease in the order SO> P2O> Al2O> Na2O. The Al2Ois atmospheric, Na2O is basic.

 

Which among the following is least acidic

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Explanation

The acidic strength of oxides decreases on moving down the group.Moreover, pentoxides are more acidic than trioxides. As the atomic no. of an element in 15 group increases, the acidic character decreases.

So,  P4O10 > As4O6 and P4O10 > As4O10 . Due to increase in O.N. of an element acidic nature increases.Thus decreasing order of acidic strength is P4O10 > P4O6  > As4O10 > As4O6 

 

Which of the following polyhalide ion is most stable

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Explanation

The stability decrease in the order I3- > Br3- > Cl3- > F3- 

In fact no F3- compounds are known,because flourine has no available d-orbitals and therefore can not expand its octet.

 

A diamagnetic element burns in air to form a dioxide.This dioxide can reduce iodine to HI. When H2 gas is bubbled through this element, it forms a hydride.It was found that the reaction of the dioxide and hydride of this element produces the same metal again.The element is

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Explanation

The given element is S.The dioxide of S is SO2 which can act as reducing agent and oxidising agent.

Point out the incorrect statement among the following :

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Explanation

Multiple bonds formation tendency with carbon and nitrogen decreases from sulphur to tellurium.

CS2 (S=C=S) is moderately stable,

CSe2 (Se=C=Se) decomposes readily whereas,

CTe(Te=C=Te) does not exist

Which of the following statements is unacceptable?

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Explanation

HClO is the weakest acid,when compared to the order acids listed.pKa =8 for HClO and for HClO4 ,pKa =1.

Moist ammonia gas is dried over

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Explanation

Because NH3 reacts with others.

2NH3 + H2SO4(NH4)2SO42NH3+P2O5 +H2O 2NH4PO3CaCl2 +4NH3 CaCl24NH3

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