The complex showing a spin-only magnetic moment of 2.82 B.M. is:
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Atomic number of Cr and Fe are respectively 24 and 26 which of the following is paramagnetic with the spin of electron?
The compound which does not show paramagnetism is:
(d) N2O4,a diamagnetic
A solution containing 2.675g of CoCl3.6NH3(molar mass=267.5g mol-1) is passed through a cation exchanger. The chloride ions obtained in solution were treated with excess of AgNo3 to give 4.78g of AgCl(molar mass=143.5g mol-1). The formula of the complex is:(At.mass of Ag=108u)
(b) Meq.of Cl- outside the sphere
= mole of Cl-
=0.033 mole of Cl-
.. Wcl=1.185g
or 0.01 mole of complex gives 0.01xn mole of Cl-
.. 0.01xn=0.033 .. n=3
Thus, formula is [CO(NH3)6]Cl3
Trunbull's blue is :
(b) Turnbull's blue is KFeII[FeIII(CN)6]
The correct IUPAC name of AlCl3(EtOH)4 is :
(b)
Follow IUPAC rules
write cationic part first, thn go for anionic part
Which complex has square planar shape dsp2 hydridizatiop?
(d) All involve dsp2-hybridization
Which has regular tetrahedral geometry?
(c) [BF4]- has sp3-hybridization and tetrahedral.
The primary valency of Fe in K3[Fe(Cn)6] is:
(a) According to Werner's theory, the primary valency of a metal is equal to the no. of charge on complex ion,i.e, 3 on [Fe(Cn)6]3-
The IUPAC name for the complex [Co(NO2)(NH3)5]Cl2 is:
(d)
n nitro , becoz N is donating electron to metal
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