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[Mn(CO)4NO] is diamagnetic because:

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Explanation

 [Mn+1(CO)4(NO-)] : Paramagnetic due to presence of unpaired e- in NO- [Mn-1(CO)4(NO+)] : No. of unpaired e- either on ligands or on Mn-1 hence it is diamagnetic

If CO ligands are substituted by NO in respective neutral carbonyl compounds then which of the following will not be correct formula ?

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Explanation

(d) Ligand NO is 3e- donar hence three CO ligands can be substituted by two NO ligands.

Which of the following species can act as reducing agent ?

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Explanation

(b) Mn(CO)6 can act as reducing agent because the metal carbonyl is stable when EAN is equal to nearest noble gas configuration.

[Mn(CO)6]-e- [Mn(CO)6]+EAN =37              EAN=36(less stable)           (more stable)

What is electronic arranegment of metal atom/ionin octahedral complex with d4 configuration , if 0< pairing energy ?

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Which of the following statement is not correct ?

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Explanation

(c) [Ni(CN)4]4- ; sp3;Tetrahedral complex.

Give the correct of initial or F for following statements. Use is statement is true and if it is false

(I) Co(III) is stabilised in presence of weak ligands , while Co(II) is stabilised in presence of strong field ligand.

(II) Four coordinated complexes of Pd(II) and Pt(II) are diamagnetic and square planar.

(III) [Ni(CN)4]4- ion and [Ni(CO)4] are diamagnetic tetrahedral and square planar.

(IV) Ni2+ ion does not inner orbital octahedral complexes.

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Match List-I with List-II and select the correct answer using the codes given below :

                      List-I                                              List-II

(I) [FeF6]3-                                                   (A) 1.73 BM

(II) [Ti(H2O)6]3+                                             (B) 5.93 BM

(III) [Cr(NH3)6]3+                                            (C) 0.00 BM

(IV) [Ni(H2O)6]2+                                             (D) 2.83 BM

(V)  [Fe(CN)6]4-                                               (E) 3.88 BM

          (I)    (II)   (III)   (IV)   (V)                       (I)    (II)   (III)   (IV)   (V) 

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Explanation

The correct matching is: (I) [FeF₆]³⁻ - (B) 5.93 BM (high spin d⁵ configuration), (II) [Ti(H₂O)₆]³⁻ - (A) 1.73 BM (d¹ configuration), (III) [Cr(NH₃)₆]³⁺ - (E) 3.88 BM (d³ configuration), (IV) [Ni(H₂O)₆]²⁺ - (D) 2.83 BM (d⁸ configuration), (V) [Fe(CN)₆]⁴⁻ - (C) 0.00 BM (diamagnetic, low spin d⁶ configuration).

Set of d-orbitals which is used by central metal during formation of MnO4-?

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Explanation

The central metal atom manganese (Mn) in the MnO4- ion has an oxidation state of +7. According to the aufbau principle, the five 3d orbitals (dxy, dyz, dxz, dx2-y2, dz2) are progressively filled. In the +7 oxidation state, Mn has a d0 configuration, meaning all 3d orbitals are vacant. Therefore, the set of d-orbitals used by the central metal during the formation of MnO4- is dxy, dyz, and dxz.

FeSO4 is a very good absorber for NO, the new compound formed by this process is found to contain number of unpaired electrons:

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Explanation

(c) Fe2+(aq)+NO+SO42-[Fe(H2O)s(NO)]2++SO42-

μeff=3.89 BM

Hence, no. of unpaired electrons = 3 

A[M(H2O)6]2+ complex typically absorbs at around 600 nm. It is allowed to react with ammonia to form a new complex [M(NH3)6]2+ that should have absorption at :

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Explanation

(b) As NH3 is stronger ligand than H2O, hence CFSE value for [M(NH3)6]2+> CFSE of[M(H2O)6]2+ therefore, absorption shifts to smaller wavelength . Also difference between splitting power of  NH3 and H2O is not very high.

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