is diamagnetic because:
: Paramagnetic due to presence of unpaired in : No. of unpaired either on ligands or on hence it is diamagnetic
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is diamagnetic because:
: Paramagnetic due to presence of unpaired in : No. of unpaired either on ligands or on hence it is diamagnetic
If CO ligands are substituted by NO in respective neutral carbonyl compounds then which of the following will not be correct formula ?
(d) Ligand NO is donar hence three CO ligands can be substituted by two NO ligands.
Which of the following species can act as reducing agent ?
(b) can act as reducing agent because the metal carbonyl is stable when EAN is equal to nearest noble gas configuration.
What is electronic arranegment of metal atom/ionin octahedral complex with configuration , if < pairing energy ?
Which of the following statement is not correct ?
(c) ; ;Tetrahedral complex.
Give the correct of initial T or F for following statements. Use T is statement is true and F if it is false
(I) Co(III) is stabilised in presence of weak ligands , while Co(II) is stabilised in presence of strong field ligand.
(II) Four coordinated complexes of Pd(II) and Pt(II) are diamagnetic and square planar.
(III) ion and are diamagnetic tetrahedral and square planar.
(IV) ion does not inner orbital octahedral complexes.
Match List-I with List-II and select the correct answer using the codes given below :
List-I List-II
(I) (A) 1.73 BM
(II) (B) 5.93 BM
(III) (C) 0.00 BM
(IV) (D) 2.83 BM
(V) (E) 3.88 BM
(I) (II) (III) (IV) (V) (I) (II) (III) (IV) (V)
The correct matching is: (I) [FeF₆]³⻠- (B) 5.93 BM (high spin dâµ configuration), (II) [Ti(Hâ‚‚O)₆]³⻠- (A) 1.73 BM (d¹ configuration), (III) [Cr(NH₃)₆]³⺠- (E) 3.88 BM (d³ configuration), (IV) [Ni(Hâ‚‚O)₆]²⺠- (D) 2.83 BM (d⸠configuration), (V) [Fe(CN)₆]â´â» - (C) 0.00 BM (diamagnetic, low spin dâ¶ configuration).
Set of d-orbitals which is used by central metal during formation of ?
The central metal atom manganese (Mn) in the MnO4- ion has an oxidation state of +7. According to the aufbau principle, the five 3d orbitals (dxy, dyz, dxz, dx2-y2, dz2) are progressively filled. In the +7 oxidation state, Mn has a d0 configuration, meaning all 3d orbitals are vacant. Therefore, the set of d-orbitals used by the central metal during the formation of MnO4- is dxy, dyz, and dxz.
is a very good absorber for NO, the new compound formed by this process is found to contain number of unpaired electrons:
(c)
Hence, no. of unpaired electrons = 3
complex typically absorbs at around 600 nm. It is allowed to react with ammonia to form a new complex that should have absorption at :
(b) As is stronger ligand than , hence CFSE value for > CFSE of therefore, absorption shifts to smaller wavelength . Also difference between splitting power of and is not very high.
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