In an SN1 reaction on chiral centres there is
(b) In SN1 reaction, there is slight more inversion product than retention product because SN1 reaction also depends on shielding effect of the front side of the reacting carbon.
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In an SN1 reaction on chiral centres there is
(b) In SN1 reaction, there is slight more inversion product than retention product because SN1 reaction also depends on shielding effect of the front side of the reacting carbon.
Following is the list of some aromatic compounds. Select the correct sequence of decreasing order of reactivity for electrophilic arpmatic substitution reaction using the answer codes given below:
a.
b.
c.
d.
Answer codes :
Dear OH is more Electronically rich ring as OH is +R group....
Then CH3 group because it Electron donating group by +I effect
Then CHO then NO2 because CHO is less Electron withdrawing group than NO2....
Consider the following statements:
a. Benzene gives substitution reaction more readily than addition reaction.
b. In benzyne mechanism reaction intermediate is carbanion also.
c. Tertiary alcohol always gives SNI reaction.
d. Reactivity of alcohol is very poor for SN reaction because alcohol is strongly acidic in character.
Of these statements :
Consider the following statements :
a. group is o, p-directing group due to hyperconjugation.
b. is meta directing group due to reverse hyperconjugation.
c. group is meta directing group due to mesomeric effect.
d. CHO group is m-directing group
Of these statements :
Which among the following compounds has minimum pH value?
Among the given options, 1-butyne has the minimum pH value as the triple bond is more acidic than double and single bonds due to the greater s-character of the sp-hybridized carbon atom, making the hydrogen more acidic.
In the given reaction,
[X] will be
In which compounds addition reaction will take place according to anti-Markovnikov's rule?
(i)
(ii)
(iii)
(iv)
Select the correct answer from the codes given below:
Codes:
Alkene having following structure gives anti Markovnikov addition where Z is strong -I group.
Consider the following statements:
(i) Alkene is more reactive than alkyne for electrophilic addition reaction.
(ii) Alkyne gives nucleophilic as well as electrophilic addition reaction.
(iii) Alkyne is more reactive than alkene for nucleophilic addition reaction.
(iv) For electrophilic addition reaction, RI of alkyne is alkyl carbonation.
Of these, correct statements are:
Which compound is least reactive for nucleophilic addition reaction?
Arrange the reactivity of given carbonyl compounds in decreasing order for addition reaction:
(i)
(ii)
(iii)
(iv)
Select the correct answer from the codes given below:
Codes:
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