What is the primary reason for the decrease in ionization energies being less rapid along the 3d series compared to the increase in nuclear charge?
The NCERT states, 'nuclear charge increases from scandium to zinc but electrons are added to the orbital of inner subshell, i.e., 3d orbitals. These 3d electrons shield the 4s electrons from the increasing nuclear charge somewhat more effectively than the outer shell electrons can shield one another. Therefore, the atomic radii decrease less rapidly. Thus, ionization energies increase only slightly along the 3d series.'