What is the primary product of the reduction of oxygen at the cathode during iron corrosion?
The cathode reaction is explicitly given as: 'Cathode: $\text{O}_2\text{(g)} + 4 \text{H}^+\text{(aq)} + 4 \text{e}^- \longrightarrow 2\text{H}_2\text{O(l)}$'. Thus, water is the primary product of oxygen reduction. (Refer to the detailed explanation of iron corrosion chemistry).