What is the role of acidification in the preparation of phenol from sodium phenoxide, which is obtained from benzenesulphonic acid?
In methods like the one from benzenesulphonic acid or haloarenes, sodium phenoxide is formed. Acidification (e.g., with dilute acid) is used to protonate the phenoxide ion ($C_6H_5O^-$) to regenerate the neutral phenol ($C_6H_5OH$). The NCERT states, 'Acidification of the sodium salt gives phenol.'