Benzene reacts with $Cl_2$ in presence of $FeCl_3$ to give
Benzene reacts with chlorine ($Cl_2$) in the presence of a catalyst such as ferric chloride ($FeCl_3$) to form chlorobenzene. The reaction is an example of electrophilic aromatic substitution where the benzene ring is substituted by a chlorine atom. The chemical equation for the reaction is: $$ \text{C}_6\text{H}_6 + \text{Cl}_2 \xrightarrow{\text{FeCl}_3} \text{C}_6\text{H}_5\text{Cl} + \text{HCl} $$