Basic Principles of Orgainc Chemistry MCQs for NEET — Chemistry Questions with Answers

Practice free Basic Principles of Orgainc Chemistry (Chemistry) NEET multiple-choice questions online with instant answers and detailed explanations. No login required.

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Which one of the following is the stable structure of cyclohexatriene?

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Explanation

(d) Benzene has planar structure.

Meso tartaric acid is optically inactive due to the presence of:

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Explanation

The rotation by upper half is internally compensated by the rotation of lower half to produce inactive nature.

The property by virtue of which a compound can turn the plane of polarization of light is known as:

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Explanation

(c) It is the definition of optical activity.

The molecular formula of a saturated compound is C2H4Br2.This formula permits the existence of:

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Explanation

(c) 1,1-dibromoethane and 1,2-dibromoethane.

How many isomers could be obtained from the alkane, C6H14?

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2-methylpent-3-ene is a chiral because it has:

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Explanation

2-methylpent-3-ene does not have a center or plane of symmetry. It has a chiral carbon (C2) due to the presence of four different groups attached to it, making the molecule chiral or optically active.

The (R)- and (S)-enantiomers of an optically active compound differ in

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Explanation

(c) R and S forms of an optically active compounds differ in their behaviour towards plane polarised light. The species which rotate the plane of polarised light toward right is called R-form (rectus form) or d-form (dextro-form) and the species which rotate the plane of polarised light towards left is known as S-form (sinister-form) or L-form (laevo-form).

The cylindrical shape of an alkyne is due to 

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Explanation

(d) In alkynes C≡C is present, in such bond one sigma and two Ï€ C-C bonds are present. Sigma bond is formed by sp-hybrid orbitals whereas Ï€-bonds are formed by unhybridised orbitals.

Hence, it shows cylindrical shape.

What is decreasing order of basicity of 1°, 2° and 3° ethyl amines and ammonia?          

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Explanation

(d) As the number of alkyl groups increases, the electron density on nitrogen atom also increases, so the basic character increases but 3° amines are less basic than 2° amines due to steric hindrance of 3° amines, so the correct order of basicity is

 Ammonia < 1 < 2 <3

 NH3<C2H5NH2<(C2H5)3N<(C2H5)2NH

The shortest C-C bond distance is found in               

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Explanation

(d) Acetylene has shortest C-C bond length because it has C≡C triple bond. The bond length follows the following order

   C-C>C=C>C≡C

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