Equilibrium MCQs for NEET — Chemistry Questions with Answers

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The equilibrium constant for the reaction $N_2(g) + 3H_2(g) \rightleftharpoons 2NH_3(g)$ is $K_c$. If the temperature is increased for this exothermic reaction, what happens to the value of $K_c$?

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Explanation

The NCERT states, 'The equilibrium constant for an exothermic reaction (negative $\Delta H$) decreases as the temperature increases.' For the formation of ammonia, $\Delta H$ is negative (exothermic).

For the thermal decomposition of calcium carbonate, $CaCO_3(s) \rightleftharpoons CaO(s) + CO_2(g)$, the equilibrium constant $K_p$ at 1100 K is 2.00. What is the partial pressure of $CO_2(g)$ at equilibrium at this temperature?

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Explanation

The NCERT states, 'Kp = $pCO_2$ = $2 \times 10^5$ Pa/10^5 Pa = 2.00'. This means that $pCO_2$ divided by $10^5$ Pa equals 2.00, so $pCO_2 = 2.00 \times 10^5$ Pa. The example explicitly demonstrates this calculation for $K_p$ in the context.

An endothermic reaction has a $\Delta H > 0$. If the temperature of this reaction at equilibrium is increased, what will be the effect on its equilibrium constant ($K_c$)?

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Explanation

The NCERT specifies, 'The equilibrium constant for an endothermic reaction (positive $\Delta H$) increases as the temperature increases.'

In a heterogeneous equilibrium involving solids, such as $Ni(s) + 4CO(g) \rightleftharpoons Ni(CO)_4(g)$, why are the concentrations of pure solids not included in the equilibrium constant expression?

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Explanation

The NCERT states, 'it must be remembered that for the existence of heterogeneous equilibrium pure solids or liquids must also be present (however small the amount may be) at equilibrium, but their concentrations or partial pressures do not appear in the expression of the equilibrium constant' because they are constant. This is also implicitly shown in the $CaCO_3$ decomposition example.

Which of the following characteristics is NOT true for an equilibrium constant?

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Explanation

The NCERT explicitly states, 'An equilibrium constant does not give any information about the rate at which the equilibrium is reached.' However, it can predict the extent and direction of a reaction, and calculate equilibrium concentrations, and is temperature dependent.

For the reaction $H_2(g) + O_2(g) \rightleftharpoons 2H_2O(g)$ at 500 K, the equilibrium constant $K_c = 2.4 \times 10^{47}$. If, at a certain instant, the concentration quotient $Q_c$ is $1.0 \times 10^{40}$, in which direction will the reaction proceed?

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Explanation

The NCERT states that the direction of reaction can be predicted by the reaction quotient ($Q_c$) which is equal to $K_c$ at equilibrium. If $Q_c < K_c$, the reaction will proceed in the forward direction to reach equilibrium. Here, $1.0 \times 10^{40} < 2.4 \times 10^{47}$, so the reaction will proceed in the forward direction.

How does the equilibrium constant for the reverse reaction relate to the equilibrium constant for the forward reaction?

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Explanation

The NCERT states, 'The equilibrium constant for the reverse reaction is equal to the inverse of the equilibrium constant for the forward reaction.'

If a reaction has an equilibrium constant $K_c = 1.0$, what can be inferred about the relative amounts of reactants and products at equilibrium?

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Explanation

A $K_c$ value of 1.0 falls between $10^{-3}$ and $10^3$. As per the NCERT, in this range, 'the concentrations of the reactants and products are comparable, when the system is in equilibrium.'

When does the expression for the equilibrium constant become applicable?

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Explanation

The NCERT lists as an important feature: 'Expression for equilibrium constant is applicable only when concentrations of the reactants and products have attained constant value at equilibrium state.'

NEET 2023

Amongst the given options which of the following molecules/ions acts as a Lewis acid?

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Explanation

BF₃ has incomplete octet around B and accepts an electron pair.

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