Amount of oxalic acid present in a solution can be determined by its titration with KMnO4 solution in the presence of H2SO4. The titration gives unsatisfactory result when carried out in the presence of HCl, because HCl:
(d) HCl is also oxidised along with oxalic acid by KMnO4 .
2KMnO4 + 16HCl 2KCl + 2MnCl2 + 5Cl2 + 8H2O
2KMnO4 + 3H2SO4 + 5H2C2O4 K2SO4 + 2MnSO4 + 8H2O + 10CO2