Solutions MCQs for NEET — Chemistry Questions with Answers

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The molar freezing point constant for water is 1.86°C/mole. If 342 g of cane sugar (C12H22O11) is dissolved in 1000 g of water, the solution will freeze at 

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Explanation

ΔTf=1.86342342=1.86

ΔTf=1.86oC    

The molal freezing point constant for water is 1.86°C/m. Therefore, the freezing point of 0.1 m NaCl solution in water is expected to be [MLNR 1994]

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Explanation

ΔTf=iKfm=2×1.86×0.1=0.372

Tf=0.372oC  

The depression in freezing point of 0.01 M aqueous solutions of urea, sodium chloride and sodium sulphate is in the ratio of [Roorkee 1990; DCE 1994]

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Explanation

Concentration of particles of 0.01 M urea, NaCl and Na2SO4=0.01M,0.02M,0.03 respectively i.e., they are in the ratio 1 : 2 : 3. Hence, depression in freezing point will be in the same ratio. 

The Van't Hoff factor for 0.1 M Ba(NO3)2 solution is 2.74. The degree of dissociation is [IIT 1999]

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Explanation

          Ba(NO3)2Initial         0.1         At. eq.    (0.1x) ⇌ Ba++0xM+2NO302xm

i=(0.1x)+x+2x0.1=0.1+2x0.1=2.74=0.1+2x=0.274 or x=0.1742=0.087

%α=x0.1×100=0.0870.1×100=87%  

Assertion : Perfectly ideal solution is not possible with respect to binary solution of two liquids.

Reason : No two substances can have exactly the same nature of intermolecular forces & also of the same magnitude.

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Explanation

(A) Assertion is true, Reason is true & Reason is the correct explanation of the Assertion.

Assertion :  When a cell is placed in hypertonic solution, it shrinks.

Reason : Reverse osmosis is used for desalination of water.

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Explanation

(B) Assertion is correct because fluids present inside the cell come out due to higher vapour pressure

      inside the cell than outside the cell.

      Reason is correct because in reverse osmosis, solvent from saline water enters the pure solvent

      through semi-permeable membrane.

Assertion : The difference in the boiling points of equimolar solution of HCI and HF decreases as their

                  molarity is decreased.

Reason : The extent of dissociation decreases steadily with increasing dilution.

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Explanation

(C) Extent of dissociated increases steadily with increasing dilution.

Assertion : When 'a' mL of a 0.1 molal urea solution is mixed with another 'b' mL of 0.1 molal glucose

                   solution, the boiling point of the solution is no different from the boiling points of the

                   samples prior to mixing but if 'a' mL of 0.1 molal urea is mixed with 'b' mL of 0.1 molal HF

                   the boiling point of the mixture is different from the boiling points of the separate

                   samples.

Reason : HF is an electrolyte (weak) whereas glucose is a non electrolyte.

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Explanation

(A) As degree of dissociation of HF gets changed on dilution.

NEET 2023

Pumice stone is an example of:

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Explanation

Gas dispersed in solid → solid foam (pumice).

NEET 2023

Given below are two statements:

Statement I: The nutrient deficient water bodies lead to eutrophication.

Statement II: Eutrophication leads to decrease in the level of oxygen in the water bodies.

Choose the correct answer:

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Explanation

Eutrophication is caused by NUTRIENT-RICH (not deficient) water; it does deplete dissolved O₂.

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