A gas is found to have the formula (CO)x. Its VD is 70. The value of x must be:
(c) Molar mass = 70 x 2 =140;
(CO)x, (12+16).x =140
therefore, x=5
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A gas is found to have the formula (CO)x. Its VD is 70. The value of x must be:
(c) Molar mass = 70 x 2 =140;
(CO)x, (12+16).x =140
therefore, x=5
100 mL of PH3 when decomposed produces phosphorus and hydrogen. The change in volume is:
(a) 2PH3(g) 2P(s) + 3H2(g)
100 0 0 Before dissociation
0 - 150 After dissociation
More explanation below:
As the volume occupied by gases only depends on number of moles of gases, the answer is related to number of moles of gases produced.
Since, no temperature and pressure is given, one can assume NTP.
At NTP, the reaction produces Phosphorous(Solid) and Hydrogen(gas). Looking at the balanced equation above, 2 moles of PH3 gas would give 3 moles of H2 gas.
Therefore, there is 50% increase in number of gaseous molecules after reaction. (2 to 3 moles)
As the volume depends on number of moles, the increased volume is also 50% more than original volume.
Increase in volume = Original Volume * 50 % = 100 ml * 50% = 50ml
New Volume = Original Volume + Increase in Volume = (100 + 50) ml = 150 ml
The molality of 1M solution of NaCl ( specific gravity 1.0585 g/mL ) is:
(b) Mass of solvent = mass of solution - mass of NaCl
= 1.0585 x 1000 - 58.5
= 1058.5 - 58.5 = 1000g =1kg
m = mole of NaCl / mass of solvent in kg = 1/1 = 1
The total molarity of all the ions containing 0.1 M of CuSO4 and o.1M of Al2(SO4)3 is:
(b) Mole of Cu2+ = 0.1x1 = 0.1
Mole of S=0.1x1=0.1
Mole of Al3+ = 0.1x2=0.2
Mole of S = 0.1x3 = 0.3
Total moles of ions present in1 litre =0.7
Molarity of all ions = 0.7M
A 0.1097 gm sample of As2O3 require 26.10 ml of KMnO4 solution for its titration. The molarity of KMnO4 solution is
In this redox titration, KMnO4 oxidizes As2O3 to H3AsO4. The balanced equation is: 2KMnO4 + 5As2O3 + 3H2SO4 → 2MnSO4 + 5H3AsO4 + K2SO4. Given: Mass of As2O3 = 0.1097 g, Volume of KMnO4 = 26.10 ml. Using the mole ratio from the balanced equation, we can calculate the molarity of KMnO4 as 0.018 M.
A sample of CaCO3 is 50% pure. On heating 1.12 litres of CO2 (at NTP) is obtained. Residues left (assuming non-volatile impurity) is , (Ca = 40, C= 12, O=16)
Solution approach
CaCO3 → CaO + CO2 (decomposition reaction for 50% pure part on heating)
The impure part doesn't react as per the question, it remains as it is. So, total residue after heating will be
1) mass of the impure part + mass of CaO (left from pure part)
since vol of CO2
suggest that moles are 1.12/22.4 = 0.05 moles
so wt of = 0.05 .100 = 5 gram. since 50 % is impure , so 5 gram is impure
You will get mass of impure part = 5g & mass of CaO = 2.8
So total = 5 + 2.8 = 7.8g
2SO2 + O2 2SO3 6.4 gm SO2 and 3.2 gm O2 to form SO3 . How much maximum mass of SO3 is formed?
0.5 mole of BaCl2 is reacted with 0.2 mole Na3PO4 then maximum moles of Ba3(PO4)2 formed is
3BaCl2 + 2Na3PO4 Ba3(PO4)2 +6NaCl
0.5mole 0.2 mole
Na3PO4 is the limiting reagent
2 Mole Na3PO4 2 Mole Ba3(PO4)2 +6NaCl
0.2 Mole Na3PO4 0.1 Mole Ba3(PO4)2
Rearrange the following (I to IV) in the order of increasing masses and choose answer from (1), (2), (3) and (4) (Atomic mass : N=14, O=16 Cu = 63)
I. 1 molecule of oxygen
II. 1 atom of nitrogen
III. 1 x 10-10g molecular weight of oxygen
IV. 1 x 10-10g weight of copper
1 molecule of oxygen = 32 a.m.u=32 x 1.66x 10-24g
1 atom of nitrogen =14 a.m.u=14 x 1.66x 10-24g
1 x 10-10 g molecular weight of oxygen = avg no of molecules of oxygen is 32 gram.so wt of given no is
32 x 10-14g
1 x 10-10g atomic weight of copper = 63.5 x 10-14g
So, order is II < I <III <IV
The ratio of number of atoms in 2.2g CO2 and 1.7g NH3 is
No. of atoms in 2.2 g CO2(n1) =
No. of atoms in 1.7g NH3(n2) =
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