Frequency ratio between violet (400nm) and red (750nm) radiations in the visible spectrum, is-
(C) v= c/
For violet (400nm)v1 = c / 400 x 10-9
For red (750nm) v2 = c/ 750x10-9
v1/v2 = 750/400= 15/8
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Frequency ratio between violet (400nm) and red (750nm) radiations in the visible spectrum, is-
(C) v= c/
For violet (400nm)v1 = c / 400 x 10-9
For red (750nm) v2 = c/ 750x10-9
v1/v2 = 750/400= 15/8
The minimum value of spin multiplicity possible, when =3, are
(B) Spin multiplicity = 2s+1 for minimum value no. unpaired electrons will be present so s=0.
Then Spin multiplicity = 1
Supposing the energy of fourth shell for hydrogen atom is -50a.u. (Arbitrary unit). What would be its ionization potential-
(B) Ionization potential = -E1
E4 = E1/16 = -50x16=E1
Hence ionization potential = -(-800) = 800 a.u.
Two isotopes of Boron are found in the nature with atomic weights 10.01(I) and 11.01(II). The atomic weight of natural Boron is 10.81. The percentage of (I) and (II) isotopes in it are respectively-
(A) Let x % of I(10.01) is mixed with II(11.01) and the atomic weight become 10.81. Then
(10.01)x + (11.01)(100-x)/100 = 10.81
10.01x-11.01x+1101 = 10.81x100
or -x = 1081-1101
or -x = -20 ; x= 20
So ratio = 20% and 100-20=80%
Calculate the wave-number of lines having the frequency of 5 x 1016 cycles per sec.
The wave-number is defined as the reciprocal of the wavelength, and is given by ν/c, where ν is the frequency and c is the speed of light. For a frequency of 5 x 1016 Hz and c = 3 x 108 m/s, the wave-number is (5 x 1016)/(3 x 108) = 1.666 x 108 m-1.
Which of the following set of quantum number is not valid
(A) n =1, = 2 is not valid.
Rutherford's scattering experiment is related to the size of the-
(A) The central part consisting whole of the positive charge and most of the mass caused by nucleus, it extremely small in size compared to the size of the atom.
The energy needed to convert helium atom to He +2 is -79eV. The first ionization energy of this atom is about
(C) He
I(I.E)+II(I.E) = 79eV
II(I.E) = 13.6eV x Z2 = 13.6x4eV = 54.4eV
I(I.E) = 79-54.4=24.6eV.
Which of the following has the maximum number of unpaired electons-
(D) Fe2+ has 1s2,2s22p6,3s23p63d6
configuration with 4 unpaired electron.
Arrange the following particles in increasing order of values of e/m ratio: Electron(e), proton(p), neutron(n) and -particle()
(B) Electron Proton Neutron -particle
e 1 unit 1 unit zero 2 units
m 1/1837 unit 1 unit 1 unit 4 unit
e/m 1837 1 zero 1/2
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