For exothermic reaction to be spontaneous (=negative)
For spontaneous reaction, should be -ve.
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For exothermic reaction to be spontaneous (=negative)
For spontaneous reaction, should be -ve.
'The free energy change due to a reaction is zero when
At eqm, no net reaction takes place so no change in energy.
An ideal gas expands at a constant external pressure of 2.0 atmosphere by 20 litre and absorbs 10kJ of heat from surrounding. What is the change in internal energy of the system:-
U = q + W
= q - PV = 10x1000 -2(20) x101.3 = 5948 J
The temperature of an ideal gas expansion increases in an:-
In adiabatic compression, work is converted into heat because the transfer of heat is not allowed.
36 ml of pure water takes 100 sec to evaporate from a vessel and heater connected to an electric source which delivers 806 watt. The of H2O is:-
1 watt = 1 J/sec
Total heat supplied for 36 ml H2O = 806 x 100 = 80600 J
Hvap. = 80600/36 x 18 = 40300 J/mol = 40.3 kJ/mol
5 moles of an ideal gas expands isothermally and irreversibly from a pressure of 10 atm to 1 atm against a constant external pressure of 1 atm. find the Wirr at 300 K:-
Wirr = -Pext[]
Wirr = -1 x (5 x 8.314/1000 x 300) x(1 - 1/10)
= -11.224 KJ
In the reaction at 300 K
H2(g) + Cl2(g)2HCl(g) = -185 kJ
if 2 mol of H2 completely react with 2 mole of Cl2 to form HCl. What is for this reaction:-
=0 fpr 2 mol (H2)
Predict which of the following reaction(s) has a positive entropy change?
(i) Ag+ (aq) + Cl-(aq) AgCl(s)
(ii) NH4Cl(g) NH3(g) + HCl(g)
(iii) 2NH3(g)N2(g) + 3H2(g)
ng = (+ve)
When two moles of an ideal gas (Cp, m=R) heated from 300 K to 600 K at constant pressure the change in entropy of gas () is:-
= 2 x Rln(600/300) + 2xRln(2V/V) = 7Rln2
The free energy change =0 when:-
When =0 Equilibrium
=(+ve) Non spontaneous
=(-ve) Spontaneous
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