Chemistry MCQs for NEET — Practice Questions with Answers

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The Kirchhoff's equation gives the effect of....on heat of reaction.

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Explanation

Kirchhoff's equation is:

H2-H1=CPT2-T1

 

The temperature of 5 ml of a strong acid increases by 5 when 5 ml of a strong base is added to it. If 10 ml of each is mixed, temperature should increase by-

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Explanation

When 5 ml of strong acid reacting with 5 ml of strong base net, heat evolved = H

 temperature increase = Hms

when 10 ml of each are reaction, the heat evolved = 2H;

but mass of the solution = 2m

 temperature increase = 2H2ms=Hms

The heat of neutralisation of HCl by NaOH is -55.9 kJ/mole. If the heat of neutralisation of HCN by NaOH is -12.1 kJ/mole, then energy of dissociation of HCN is-

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Explanation

The heat of neutralisation = -55.9 kJ

 The heat of neutralisation of HCN by NaOH = the heat of neutralisation + the energy of dissociation of HCN

= -12.1 kJ

or the energy of dissociation of HCN

= +55.9-12.1 = 43.8 kJ

For a reaction at equilibrium-

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Explanation

For a reaction at equilibrium G=0 and not G.

Using only the following data:

(I) Fe2O3s+3COg2Fe(s)+3CO2(g);H=-26.8 kJ

(II) Fes+COgFeOs+COg;H=+16.5 kJ

the H value, in kilojoules, for the reaction

Fe2O3s+COg2FeOs+CO2g is calculated to be:

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Explanation

from equation (I) + (2×II) ;     H= 6.2 kJ

82 litres of carbon dioxide are produced at a pressure of 1 atm by the action of acid on a metal carbonate. The work done by the gas (in calories) in pushing back the atmosphere is (R = 0.082 litre-atm deg-1mol-1)

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Explanation

The work done by a gas is given by

W= PV

Among the following, the reaction for which H=E is-

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Explanation

When n=0, H=E  because H=E+RT n.

For which change HE

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Explanation

H=E+nRT

Enthalpy change when 1.00 g water is frozen at 0C, is :

Hfus=-1.435 kcal mol-1

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Explanation

H(per g) = -1.43518 kcal =  - 0.0797 kcal g

One mole of hydrogen gas at 25C and 1 atm pressure is heated at constant pressure until its volume has doubled. Given that Cv for hydrogen is 3.0 cal deg-1 mol-1, the H and E for this process are-

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Explanation

H=CPT and E=CVT.

CP-CV=R using these equations after calculating the final temperature, the desired result is obtained.

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