Chemistry MCQs for NEET — Practice Questions with Answers

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When 36 g of a solute having the empirical formula CH2O is dissolved in 1.2 kg of water, the solution freezes at
-0.93°C. What is the molecular formula of solute (K= 1.86 kg K mol-1)

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Explanation

ΔTf= i Kf m

0.93= 1 x 1.86 x 36/M   ; M=60
                            1.2

A solution containing 0.03659 g/ml of HCl and a solution containing 0.04509 g/ml of acetic acid Then:

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Explanation

NHCl=0.03659×100036.5=1.002N

NCH3COOH=0.04509×100060=0.7515N

The relative lowering of vapour pressure caused by dissolving 71.3 g of a substance in 1000 g of water is 7.13 X 10-3. The molecular mass of the substance is :-

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Explanation

dsol.=massvolume      N=WE×1vLVsol.=1000.6ml        N=3535×1000×0.6100=6

Total vapour pressure of mixture of 1mol APA0=150 torr and 2 mol BPB0=240 torr is 200 torr. In this case:

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Explanation

The total vapor pressure of the mixture is less than the sum of the vapor pressures of the pure components (150 torr for A and 240 torr for 2 mol of B), which indicates a negative deviation from Raoult's law. This suggests that there are attractive intermolecular forces between A and B molecules, leading to a lower vapor pressure than expected.

When 0.1 m CH3COOH is present in a solvent it shows elevation in boiling point of 0.75°C. Acid dissociation constant will be -(Kb=5 K Kg mol-1) (1M =1m)

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Explanation

 

 

ΔTb=iKbm;0.75 = i×5×0.1i=1.5; α=1.5-12-1=0.5Ka=α2C1-α=0.52×0.11-0.5=5×10-2

Which of the following shows positive deviation from Raoult's law:

(i) Chloroform and acetone

(ii) Carbon disulphide and acetone

(iii) Ethanol and Acetone

(iv) Phenol and Aniline

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A non-volatile solute is dissolved in a water. If its degree of association is 50%. What will be its freezing point when boiling point is 100.52°C. [Kb=0.52 K kg mol-1, Kf=1.86K kg mol-1]

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Explanation

For a non-volatile solute, the freezing point depression (ΔTf) is given by ΔTf = Kf * m, where Kf is the cryoscopic constant and m is the molality of the solution. Given that the degree of association is 50%, the van't Hoff factor (i) is 2. Substituting the values, ΔTf = 1.86 * (100.52/100) * 2 = 3.72°C. Therefore, the freezing point will be 100.52 - 3.72 = 96.8°C or -1.86°C.

When 36 g of a solute having the emperical formula CH2O is dissolved in 1.2 kg of water, the solution freezes at -0.93°C. What is the molecular formula of solute (Kf=1.86 kg K mol-1)

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Explanation

 

 

 

Tf=ikfm0.93=1×1.86×361.2M; M=60

m is 60 gram , so 4th is right ans

How much oxygen is dissolved in 100ml water at 298K if partial pressure of oxygen is 0.5 atm and KH=1.4 X 10-3 M/atm ?

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Explanation

 

According to henry's law

S=KH X p (S=conc. of O2 dissolved)

S=1.4 ×10-3×0.5=7×10-4mol/L=w/MwVLw=7×10-4×Mw×VL        =7×10-4×32×0.1        =22.4×10-4g=2.24 mg

A solute x when dissolved in solvent associates to form a pentamer. The value of van't hoff factor (i) for the solute will be:-

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Explanation

5x x5DOA, 1-i1-1n1=1-i1-1545=1-ii=1-45=15=0.2

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