Chemistry MCQs for NEET — Practice Questions with Answers

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Three solutions are prepared by adding 'w' gm of 'A' into 1kg of water, gm of '13' into another 1 kg of water and 'w' gm of 'C' in another 1 kg of water (A, B, C are non electrolytic). Dry air is passed from these solutions in sequence (A → B → C). The loss in weight of solution A was found to be 2gm while solution B gained 0.5 gm and solution C lost 1 gm. Then the relation between molar masses of A, B and C is :

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Explanation

The loss in weight should be proportional to vapour pressure above that solution:

So, PSA 2gm

PSB 1.5gm

PSC 2.5gm

So, maximum vapour pressure is above C solution hence, it is having minimum lower and hence minimum mole fraction (hence minimum number of moles of solute) So max, molar mass of substance.

The molar heat of vapourization of toluene is AHv. If its vapour pressure at 315 K is 60 torr & that at 356K is300 torr then AHv = ? (log 2 = 0.3)

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Explanation

The molar heat of vaporization (ΔHv) can be calculated using the Clausius-Clapeyron equation: ln(P2/P1) = -(ΔHv/R) * ((1/T2) - (1/T1)). Substituting the given values and using log(5) = 0.3 * log(2), we get: ΔHv = (8.314 * 0.3 * (356 - 315)) / (1/356 - 1/315) = 37.5 kJ/mol.

Relative decrease in vapour pressure of an aqueous solution containing 2 moles [Cu(NH3)3Cl) Cl in 3 moles H2O is 0.50. On reaction with AgNO3, this solution will form (assuming no change in degree of ionisation of substance on adding AgNO3)

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Explanation

ΔPP Xsolute= i ×25=12

so, i = 1.25

⇒ Hence degree of dissociation = 14

so,moles of Cl ions 2 × 14= 12moles

so, moles of AgCl ppt = 12moles = 0.5 mol AgCl

Which of the following has been arranged in order of decreasing freezing point?

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Explanation

Higher freezing point ⇒ lesser ΔTf

⇒ lesser molality

⇒ lesser number of particles

An ideal mixture of liquids A and B with 2 moles of A and 2 moles of B has a total vapour pressure of 1 atm at a certain temperature. Another mixture with 1 mole of A and 3 moles of B has a vapour pressure greater than 1 atm. But if 4 moles of C are added to the second mixture, the vapour pressure comes down to 1 atm. Vapour pressure of C, Pc° = 0.8 atm. Calculate the vapour pressures of pure A and pure B.

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Explanation

PA02+PB02= 1 atm PA° + PB° = 2 atm

PA04+3PB04 > 1 atmrArrPA° + 3PB° > 4 atm

and PA08+3PB08 + 4PC08 = 1 atmrArrPA° + 3PB° + 4P C° = 8 atm

So PA° + 3PB° = (8 – 4 × 0.8 ) atm = 4.8 atm 

Hence PB° = 1.4 atm

PB° = 0.6 atm

A sample of air is saturated with benzene (vapor pressure = 100 mm Hg at 298 K) at 298K, 750mm Hgpressure. If it is isothermally compressed to one third of its initial volume, the final pressure of the system is

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Explanation

Pressure of air = 750 – 100 = 650 mm of Hg

on compressing Pf = 650 × 3 mm of Hg = 1950 mm of Hg

so PT = (1950 + 100) = 2050 mm of Hg

Available solutions are 1L of 0.1 M NaCl and 2L of 0.2 M CaCl2. Using only these two solutions what maximum volume of a solution can be prepared having [Cl] = 0.34M exactly. Both electrolytes are strong

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Explanation

Let volumes taken to be ‘x’ & ‘y’ litres,

so 0.1x+0.4yx+y = 0.34&Vg = (x + y) (to be maximised)

so y = 4x so for maximum volume

y = 2L & x = 12L. 

Calculate the osmotic pressure of the solution prepared in the abovequestionT = 300 K, (R = 0.082 L atm mol-1K-1)

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Explanation

π = CRT

C = (0.34 + 0.1×0.52.5+0.2×22.5)= 0.34 + 0.02 + 0.16 = 0.52

so π = 0.52 × 0.082 × 300 atm = 12.792 atm 

Consider equimolal aqueous solutions of NaHSO4 and NaCl with ATb and Arb as their respective boiling point elevations. The value of limx0ΔTbΔTb' will be :

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Explanation

As m → 0, NaHSO4 will generate three particles while NaCl will generate only two particles.

The vapor pressures of benzene, toluene and a xylene are 75 Torr, 22 Torrand 10 Torr at 20°C. Which of the following is not a possible value of the vapor pressure of an equimolar binary/ternary solution of these at 20°C ? Assume all form ideal solution with each other.

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Explanation

PT = 12(75 + 22) = 48.5 torr

PT = 12(75 + 10) = 42.5 torr

PT = 12(22 + 10) = 16 torr

PT = 13(75 + 22 + 10) = 35 23torr  

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