Three solutions are prepared by adding 'w' gm of 'A' into 1kg of water, gm of '13' into another 1 kg of water and 'w' gm of 'C' in another 1 kg of water (A, B, C are non electrolytic). Dry air is passed from these solutions in sequence (A → B → C). The loss in weight of solution A was found to be 2gm while solution B gained 0.5 gm and solution C lost 1 gm. Then the relation between molar masses of A, B and C is :
The loss in weight should be proportional to vapour pressure above that solution:
So, 2gm
1.5gm
2.5gm
So, maximum vapour pressure is above C solution hence, it is having minimum lower and hence minimum mole fraction (hence minimum number of moles of solute) So max, molar mass of substance.