Chemistry MCQs for NEET — Practice Questions with Answers

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The time for half-life of a first order reaction is 1 hr. What is the time taken for 87.5% completion of the reaction?

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Explanation

(c) 87.5% completion means 3 half lives.

Which order of reaction obeys the relation t1/2 = 1/Ka?

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Explanation

(b) For II order reaction, t = (1/K){x/a(a-x)'}

     if x = a/2, t1/2 = 1/K.a'

The chemical reaction, 2O3 3O2 proceeds as follows;

O3 O2 + O .....(Fast)

O+O3  2O2 ....(Slow)

The rate law expression should be:

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Explanation

(b) For slow step, rate = K[O3][O2]  ... (i)

Also for equilibrium Kc=[O][O2] / [O3]   .....(ii)

[O] = Kc[O3]/[O2]   .. (iii)

By Eqs. (iii) and (i) the  intermediate [O] is eliminated as rate = K.Kc[O3][O3]/[O2] = K'[O3]2 /[O2]

The rate of reaction becomes 2 times for every 10°C rise in temperature. How the rate of reaction will increase when temperature is increased from 30°C to 80°C?

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Explanation

(b) Kt+10/Kt =rt+10/rt = 2;

For an increase of temperature to 50°C, i.e, 5 times, the rate increases by 2times, i.e, 32 times

The rate constant (K) for the reaction 2A +B  Product was found to be 2.5x10-5 litre mol-1 sec-1 after 15 sec, 2.60 x10-5 litre mol-1sec-1 after 30 sec and 2.55 x10-5litre mol-1 sec-1 after 50 sec. The order of reaction is:

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Explanation

(a) K does not change with time; also unit of K suggest it to be II order 

     Now, r = k[A] = 10-2x0.1 = 102Msec-1

 

A reaction A2 + B2  2AB occurs by the following mechanism;

A2  A + A               .....(slow)

A + B2  AB + B       .....(fast)

A + B  AB               .....(fast)

Its order would be:

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Explanation

(b) rate = K[ A2]

For a given reaction, presence of catalyst reduces the energy of activation by 2 kcal at 27°C. The rate of reaction will be increased by:

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Explanation

K1=Ae-Ea/RTK2=Ae-[Ea-2]/RTK1K2=e2/RT=e2/2×10-3×300=28

What fraction of a reactant showing first order remains after 40 minute if t1/2 is 20 minute?

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Explanation

N=N0/2n

n=T/tN1/2=40/20=2

N=N0/22=N0/4

Rate equation for a second order reaction is:

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Explanation

(c) dx/dt = K(a-x)2 is differential form of II order. Integrate it to get (c).

For the reaction 2NO2 + F2 → 2NO2F, following

mechanism has been provided,

 NO2 + F2   slow  NO2F+F

NO2 + F   fast NO2F

Thus, rate expression of the above

reaction can be written as:

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Explanation

(b) Slowest step of mechanism decides the rate expression, thus, rate = K[NO2][F2]

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