Chemistry MCQs for NEET — Practice Questions with Answers

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Total number of stereisomers of [Co(acac)2BrCl] are:

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Explanation

The coordination compound [Co(acac)2BrCl]⁺ has a cobalt(III) center with an oxidation state of +3. It exhibits geometrical isomerism due to the presence of different ligands (acac, Br, and Cl). The total number of stereoisomers is 3: two optically active enantiomers and one optically inactive meso form.

Which of the following complex compound exhibits geometrical isomerism?

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Explanation

(c) [PdClBr(gly)] is square planar complex hence it can exhibits geometrical isomerism.

In which case racemic mixture is obtained on mixing its mirror images (d & l form) in 1:1 molar ratio?

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Explanation

(a)  trans-[Co(gly)3] is optically active complex , hence equimolar mixture of 'd' and 'l' form on mixing gives racemic mixture.

Which of the following compound shows optical isomerism?

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Explanation

The complex compound [Co(en)3]³⁺ (en = ethylenediamine) exhibits optical isomerism due to the presence of three bidentate ethylenediamine ligands. The arrangement of these ligands around the cobalt(III) center leads to two non-superimposable mirror image isomers, known as enantiomers, which exhibit optical activity.

Which of the following is correct IUPAC name of any complex compound?

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A complex cation is formed by Pt (in some oxidation state) with ligands (in proper number so that coordination number of Pt becomes six). Which of the following can be its correct IUPAC name?

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Explanation

 C    A PtenSCN2NH320 ; it is not ion          B PtenSCN2NH322+ ; it should not be platinate          C correct name          D Pten2SCN2NH322+ ; its coordination number  = 8

Which of the following is not correctly matched?

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Explanation

(A) Na2Credta.

The EAN of metal atoms in FeCO2NO+2 and (Co)2(CO)8 respectively are :

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Explanation

   Oxidation state of iron in Fe-2CO02NO+2=x+20+2=0; x=-2         So EAN =28+8=36         Oxidation state of cobalt in Co2CO8=2x +8-0= or x=0         So EAN =27+1+8=36.

In Co2 (CO)8, divided elecrons in 2 half, basically its a Co(CO)4 with one Co -Co bond, whose 1 electron will be added to either part 

Match the complex ions listed in column-I with the characteristics listed in column-II using the codes given below.

Column-I                                                        Column-II

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Which of the following statements is correct?

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