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An evacuated glass vessel weighs 50.0 g when empty, 148.0 g when filled with a liquid of density 0.98 g mL1 and 50.5 g when filled with an ideal gas at 760 mm Hg at 300 K. Determine the molar mass or the gas.

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Explanation

C.   Mass of water filled in the glass vessel,          m1=148.0-50.0g =98.0 g          Volume of glass vessel,          V=m1ρ=98.0 g0.98 g mol-1= 100 mL = 0.1 dm3          Mass of gas filled in the vessel, m = 50.5  50.0g = 0.5 g           If M is the molar mass of the gas, we will have          pV=nRT=mMRT         or M=mRTpV         =0.5g8.314 J K-1 mol-1300 K101.325 kPa0.1 dm3=123 g mol-1

The average speed at T1 (in kelvin) and the most probable speed at T2 (in kelvin) of CO2 gas is 9.0 × 104 cm s1. Calculate the values of T1 and T2.

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Explanation

A.   We have uav=8RTπM          Hence, 8RT1πM=9.0×104 cm s-1          or T1=9.0×102 m s-12πM8R=9.0×102 m s-12         3.1444×10-3 kg mol-188.314 J K-1 mol-1=1682.5 K         For most probable speed, we have         3RT2M=9.0×102 m s-1          Hence, T2=9.0×102 m s-12M2R         =9.0×102 m s-1244×10-3 kg mol-128.314 J K-1 mol-1=2143.4 K

Two flasks of equal volume connected by a narrow tube (of negligible volume) at 27ºC and contain 0.70 mole of H2 at 0.5 atm. One of the flasks is then immersed into a hot bath, kept at 127ºC, while the other remains at 27ºC. Calculate the final pressure.

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Explanation

(B). Each flask initially contains 0.35 mole of H2

      Let ‘x’ moles of hydrogen gas be diffused from flask II to flask I

      No. of moles of H2 in flask I = (0.35 + x)

      No. of moles of H2 in flask II = (0.35 – x)

      If the new pressure is P, then

      In flask I, PV = (0.35 + x) × R × 300

      In flask II, PV = (0.35 – x) × R × 400 x = 0.05

      If volume of each flask is ‘V’ litre V = 17.241 L

      So, P × 17.241 = 0.30 × 0.0821 × 400P = 0.5714 atm

A certain sample of gas has a volume of 0.2 litre measured at 1 atm pressure and 0°C. At the same pressure but at
273°C, its volume will be:

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Explanation

1)

when temp became twice, vol will become twice ( Boyle's law)

A certain hydrate has the formula MgSO4, xH2O. A quantity of 54.2 g of the compound is heated in an oven to drive off the water. If the water vapour generated exerts a pressure of 24.8 atm in a 2.0 L container at 120°C, calculate x.

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Explanation

PV = nRT , n =  moles of water vapour

n=PVRT=24.8×20.0821×393=1.53 moles

wt of MgSO4 = 54-27.6 = 26.5

1.

MgSO4

26.5120

0.22

0.220.22=1

2.

H2O

27.618

1.53

4.530.227

 

 

A mixture of Ne and Ar at 250 K has a total K.E.=3 kJ in a closed vessel, the total mass if Ne and Ar is 30 g. Find mass % of Ne in a gaseous mixture at 250 K.

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Explanation

4.

Let x be the mass of Ne and y be the mass of Ar

x + y = 30                                 ...(i)

The molar mass of Ar = 40 g

The molar mass of Ne = 20 g

Moles of Neon + moles of Argon = Total noles

x20 + y40 = nTotal of K.E. = 32nRTGiven,K.E. = 3 KJ, T = 250 K, R = 8.314 J K-1 mol-13000 J = 32x20 + y40 × 8.314 ×2502x + y = 38.48                             ...iiFrom i and ii     y = 21.52 gmass of Neon = Massof neonTotal mass × 100                          = 8.4830 × 100 = 28.3%

In two vessels of 1 litre each at the same temperature 1 g of H2 and 1 g of CH4 are taken, for these:

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Explanation

K.E = 3/2 RT, so does not depend on moles

At what temperature will average speed of the molecules of the second member of the series CnH2n be the same of Cl2 at 627°C?

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Explanation

Second memeber of CnH2n series    = C3H6=42    = 8RT1πM1=8RT2πM2=90071=T242             T2=532.4 K

If URMS of a gas is 30 R1/2 ms-1 at 27°C then the molar mass of gas is:

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Explanation

Urms=3RTMor  30R12=3RTMor  302=300×3MM=1.0 g mol-1=0.001 kg mol-1Hence answer is d

The compressibility factor for nitrogen at 330 K and 800 atm is 1.90 and at 570 K and 200 atm is 1.10. A certain mass of N2 occupies a volume of 1 dm3 at 330 K and 800 atm. Calculate volume occupied by same quantity of N2 gas at 570 K and 200 atm:

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Explanation

Z=PVnRT;    1.90=1×800n×R×330;                n=1×8001.90×R×330             Z=1.10=V×200n×R×570;                   1.10=V×200×1.90×R×330800×R×570                   V=4 L

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