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In which of the following oxoanions the oxidation state of the central atom is not the same as that of its group number in the periodic table?

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Explanation

(D)

     (A) MnO4-=+7; Ar18 3d5 4s2=7.                             (B) Cr2O72-=+6; Ar18 3d5 4s1=6.

     (C) VO43-=+5; Ar18 3d3 4s2=5.                               (D) FeO42-=+6; Ar18 3d6 4s2=8.

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At 300°C, FeCl3 :

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Explanation

  True statement, 2FeCl3→   300°C   FeCl32g

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Anhydrous ferric chloride is prepared by

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Explanation

(B)

    (B) 2Fe+3Cl2→                 2FeCl3anhydrous; A, C, D do not give anhydrous FeCl3 but 

    hydrated FeCl3.

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Anhydrous ferrous sulphate on heating gives :

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FeCl3.6H2O+C CH32CH3O2→Products

Reaction products are :

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Explanation

(A)   FeCl3.6H2O+CH-C||OCH3OCH3-CH3→FeCl3+12CH3OH+6CH3COOH3

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Excess of Kl reactions with CuSO4 solution and Na2SO4 solution is added to it. Which of the following statement is incorrect for this reaction ?

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Explanation

(B)

     2CuSO4+4Kl→             2K2SO4+Cu2I2+I22Na2S2O3+I2→            Na2S4O6+2NaI; CuI2 is not formed according to following reaction.2CuI2unstable→            Cu2I2+I2.

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Select the correct statement :

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Explanation

(D)

     (A) AgNO3+PH3→         Ag↓+HNO3+H3PO3

     (B) AgNO3→Organic tissue proteinsAg↓black

     (C) Ag+2KCN→        AgCN2+

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The yellow colour solution of Na2CrO4 changes to orange-red on passing CO2 gas due to the formation of :

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Explanation

(C)  CO2+H2O→        H2CO3⇌2H++CO42-; CrO42-+2H+⇌Cr2O72-orange red+H2O

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FeCr2O4+4Na2CO3+O2→FusionX→   H2O   H+Y→H2O2H+Z

Which of the following statements is true for the compounds [X], [Y] and [Z] ?

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Explanation

(D)

4FeCr2O4+8Na2CO3+7O2→FusionNa2Cr+VIO4→H2OH+Na2Cr2+VIO7→     H+/H2O2Cr+VIOO22deep blue violet→H2OO2+H2O+Cr3+.

Na2Cr2O7+H2O4→            2CrO3chronic anhydride + Na2SO4+H2O.

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KMnO4 on treatment with conc. H2SO4 forms a compound (X) which decomposes explosively on heating forming (Y). The (X) and (Y) are respectively :

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Explanation

(A) 

     2KMnO4+3H2SO4→        2KHSO4+MnO32 SO4+2H2O

     MnO32SO4+H2O→           Mn2O7+H2SO4

      Mn2O7→    ∆    2MnO2+3O2

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