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In which of the following oxoanions the oxidation state of the central atom is not the same as that of its group number in the periodic table?

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Explanation

(D)

     (A) MnO4-=+7; Ar18 3d5 4s2=7.                             (B) Cr2O72-=+6; Ar18 3d5 4s1=6.

     (C) VO43-=+5; Ar18 3d3 4s2=5.                               (D) FeO42-=+6; Ar18 3d6 4s2=8.

At 300°C, FeCl3 :

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Explanation

  True statement, 2FeCl3   300°C   FeCl32g

Anhydrous ferric chloride is prepared by

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Explanation

(B)

    (B) 2Fe+3Cl2                 2FeCl3anhydrous; A, C, D do not give anhydrous FeCl3 but 

    hydrated FeCl3.

Anhydrous ferrous sulphate on heating gives :

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FeCl3.6H2O+C CH32CH3O2Products

Reaction products are :

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Explanation

(A)   FeCl3.6H2O+CH-C||OCH3OCH3-CH3FeCl3+12CH3OH+6CH3COOH3

Excess of Kl reactions with CuSO4 solution and Na2SO4 solution is added to it. Which of the following statement is incorrect for this reaction ?

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Explanation

(B)

     2CuSO4+4Kl             2K2SO4+Cu2I2+I22Na2S2O3+I2            Na2S4O6+2NaI; CuI2 is not formed according to following reaction.2CuI2unstable            Cu2I2+I2.

Select the correct statement :

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Explanation

(D)

     (A) AgNO3+PH3         Ag+HNO3+H3PO3

     (B) AgNO3Organic tissue proteinsAgblack

     (C) Ag+2KCN        AgCN2+

The yellow colour solution of Na2CrO4 changes to orange-red on passing CO2 gas due to the formation of :

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Explanation

(C)  CO2+H2O        H2CO32H++CO42-; CrO42-+2H+Cr2O72-orange red+H2O

FeCr2O4+4Na2CO3+O2FusionX   H2O   H+YH2O2H+Z

Which of the following statements is true for the compounds [X], [Y] and [Z] ?

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Explanation

(D)

4FeCr2O4+8Na2CO3+7O2FusionNa2Cr+VIO4H2OH+Na2Cr2+VIO7     H+/H2O2Cr+VIOO22deep blue violetH2OO2+H2O+Cr3+.

Na2Cr2O7+H2O4            2CrO3chronic anhydride + Na2SO4+H2O.

KMnO4 on treatment with conc. H2SO4 forms a compound (X) which decomposes explosively on heating forming (Y). The (X) and (Y) are respectively :

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Explanation

(A) 

     2KMnO4+3H2SO4        2KHSO4+MnO32 SO4+2H2O

     MnO32SO4+H2O           Mn2O7+H2SO4

      Mn2O7        2MnO2+3O2

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