Assertion : The number of unpaired electrons in the following gaseous ions:
are 4, 3, 2 and 1 respectively
Reason : is stable in aqueous solution.
(B) is most
stable due to greater CFSE of configuration.
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Assertion : The number of unpaired electrons in the following gaseous ions:
are 4, 3, 2 and 1 respectively
Reason : is stable in aqueous solution.
(B) is most
stable due to greater CFSE of configuration.
Assertion : Cuprous ion is colourless whereas cupric ion produces blue colour in solution.
Reason : Cuprous ion has unpaired electrons while cupric ion does not.
(C) Cupric ion produces blue colour in solution due to the presence of unpaired electron (d-d transition)
while cuprous ion does not have unpaired electron.
Assertion : Ammonical silver nitrate converts glucose to gluconic acid and metallic silver is precipitated.
Reason : Glucose acts as a weak reducing agent.
(A)
Assertion : To a solution of potassium chromate if a strong acid is added it changes its colour from
yellow to orange.
Reason : The colour change is due to the oxidation of potassium chromate.
There is no change in oxidation state. So the explanation is wrong.
Which one of the following statements is not correct
Always transition metals combines with more than one carbonyl group.
Which of the following pairs of compounds are more stable
By comparing the value of ionization energies the thermodynamic stability of transition metal compound can be compared. Ionization value shows that Ni(II) compound are more stable than Pt(II) compund while Pt(IV) compound are relatively more stable than Ni(IV).
The radius of La3+ (atomic number of La=57) is 1.06 . Which one of the following given values will be closest to the radius of Lu3+ (atomic number of Lu =71)
The ionic radius of Lu3+ is 0.87 , which is very close to the value 0.85 .This decrease in the ionic radius is due to lanthanoid contraction.
By calculating Eo value of the following reaction,which one of the following reaction are spontaneous.
Given
Which of the following has maximum number of unpaired electrons?
Fe3+ has the maximum number of unpaired electrons (5 unpaired electrons) among the given options. The electronic configuration of Fe3+ is [Ar] 3d5, where all five 3d electrons are unpaired, aligning their spins parallel due to the strong exchange energy.
The atomc number of potassium is 19 & that of manganese is 25. Although the colour of MnO4- is dark violet yet the K+ is colourless.This is due to the fact that
In [MnO4]- the oxidation state of Mn is +7 (do configuration),expected to be colourless but [MnO4]- is coloured due to transfer of charge from oxygen to manganese.
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