NEET Practice Questions (MCQs) with Answers & Solutions

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Hydrolysis of alkyl isocyanide yields

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Explanation

R-NC + 2H2O H+ R-NH2 + HCOOH

                                   1° Amine

Reaction of R-C||O-NH2 with a mixture of Br2 and KOH gives R-NH2 as the main product. The intermediates involved in this reaction are: 

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Which of the following alkene cannot be prepared by de-amination of n-Bu-NH2 with NaNO2/HCl ?

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Explanation

Deamination of n-Bu-NH2 using NaNO2/HCl gives a mixture of 1-butene, cis-2-butene, and trans-2-butene. The formation of isobutene is not possible as it requires a rearrangement which does not occur under these conditions.

Deamination (or) diazotization of n-Bu-NH2 with NaNO2/HCl gives ......... isomeric butene.

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Explanation

Deamination (or diazotization) of n-Bu-NH2 with NaNO2/HCl gives a mixture of three isomeric butenes: 1-butene, cis-2-butene, and trans-2-butene. Therefore, the answer is 3 isomeric butenes.

Lassaigne's test for the detection of nitrogen will fail in the case of :

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Explanation

(C) NH2-NH(inorganic compound give -ve Lassaigne's test)

Identify the product (A)  in following reaction series,

CH3CN Na/C2H5OH(X) HNO2(Y) [O](Z) Tollens reagent(A):

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Explanation

(c) CH3CN Na/C2H5OH CH3CH2NH HNO2CH3CH2OH[O] CH3CHO Tollens reagentCH3COOH

The product C of the reaction,

     CH3CNH2OANH3BC is:

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Explanation

(d) CH3CNH2OCH3COOHNH3CH3COONH4CH3CONH2+H2O

Gabriels phthalimide reaction is used to prepare:

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Gas evolved during the reacton of sodium metal on ethyl-amine is:

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Explanation

(c) C2H5NH2 1+ Na       C2H5NHNa + 12H2

Ethylamine undergoes oxidation in the presence of KMnOfollowed by hydrolysis to form:

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Explanation

 C2H5NH2OCH3CH=NHKOHCH3CHO + NH3

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