NEET Practice Questions (MCQs) with Answers & Solutions

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Hydrolysis of alkyl isocyanide yields

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Explanation

R-NC + 2H2O →H+ R-NH2 + HCOOH

                                   1° Amine

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Reaction of R-C||O-NH2 with a mixture of Br2 and KOH gives R-NH2 as the main product. The intermediates involved in this reaction are: 

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Which of the following alkene cannot be prepared by de-amination of n-Bu-NH2 with NaNO2/HCl ?

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Explanation

Deamination of n-Bu-NH2 using NaNO2/HCl gives a mixture of 1-butene, cis-2-butene, and trans-2-butene. The formation of isobutene is not possible as it requires a rearrangement which does not occur under these conditions.

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Deamination (or) diazotization of n-Bu-NH2 with NaNO2/HCl gives ......... isomeric butene.

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Explanation

Deamination (or diazotization) of n-Bu-NH2 with NaNO2/HCl gives a mixture of three isomeric butenes: 1-butene, cis-2-butene, and trans-2-butene. Therefore, the answer is 3 isomeric butenes.

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Lassaigne's test for the detection of nitrogen will fail in the case of :

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Explanation

(C) NH2-NH2 (inorganic compound give -ve Lassaigne's test)

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Identify the product (A)  in following reaction series,

CH3CN →Na/C2H5OH(X) →HNO2(Y) →[O](Z) →Tollens reagent(A):

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Explanation

(c) CH3CN →Na/C2H5OH CH3CH2NH2  →HNO2CH3CH2OH→[O] CH3CHO →Tollens reagentCH3COOH

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The product C of the reaction,

     CH3CN→H2OA→NH3B→∆C is:

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Explanation

(d) CH3CN→H2OCH3COOH→NH3CH3COONH4→∆CH3CONH2+H2O

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Gabriels phthalimide reaction is used to prepare:

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Gas evolved during the reacton of sodium metal on ethyl-amine is:

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Explanation

(c) C2H5NH2 1+ Na →      C2H5NHNa + 12H2

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Ethylamine undergoes oxidation in the presence of KMnO4 followed by hydrolysis to form:

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Explanation

 C2H5NH2→OCH3CH=NH→KOHCH3CHO + NH3

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