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Mendius method of preparation of amines consists of: 

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Explanation

(a) R-CN ReductionRCH2CH2

The correct order of basicities of the following compounds is:

CH3-C||||NH2NH1,  CH3CH2NH22 , CH32NH3 ,  CH3-C||O-NH24

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Explanation

 Negative charge developed on N in the resonance hybride makes it more basic as it loses electron pair readily. Also 2° amine is more basic than 1° amine due to +ve IE of alkyl group. In amide, the lone pair remains less avaible due to delocalisation is resonance.

A primary amine heated with CS2 in presence of excess of HgCl2 gives isothiocyanate. The reaction is called:

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Explanation

The reaction of a primary amine with carbon disulfide (CSâ‚‚) in the presence of excess mercuric chloride (HgClâ‚‚) to form an isothiocyanate is known as the Hofmann's mustard oil reaction. This reaction is used to synthesize isothiocyanates, which have a characteristic pungent odor.

Reaction of cyclohexanone with dimethylamine in the presence of catalytic amount of an acid forms a compound if water during the reaction is continuously removed. The compound formed is generally known as:

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Biuret test is not given by: 

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Explanation

The Biuret test is a chemical test used to detect the presence of peptide bonds in proteins and polypeptides. It involves treating the sample with a copper(II) salt solution and observing a violet or pink color change. Carbohydrates do not contain peptide bonds, so they do not give a positive Biuret test.

An aromatic amine (A) was treated with alcoholic potash and another compound (Y) when a foul smelling gas was formed with formula C6H5NC. (Y) was formed by reacting a compound (Z) with Cl2 in the presence of slaked lime. Compound (Z) is:

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Explanation

C6H5NH2 + KOH (Y) C6H5NC; (Y) is CHCl3; (Y) is formed from (Z) + Cl2 + Ca(OH)and thus (Z) is CH3COCH3.

Aniline was acetylated. The product on nitration followed by alkaline hydrolysis gave:

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Explanation

Aniline, when acetylated, forms acetanilide. Nitration of acetanilide gives a mixture of o-nitroacetanilide and p-nitroacetanilide. Alkaline hydrolysis of these compounds removes the acetyl group, giving a mixture of o-nitroaniline and p-nitroaniline.

Pyridine possesses :

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Explanation

Pyridine is an aromatic heterocyclic compound consisting of a six-membered ring with five carbon atoms and one nitrogen atom. The presence of the delocalized π-electron system in the ring gives pyridine its aromatic nature, similar to benzene.

Ammoniacal solution of Ni(CN)2 reacts with C6H6 to produce a light violet coloured crystaline compound of the formula:

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The reaction, C6H5N2Cl Cu2Cl2/HClC6H5Cl + N2 is called:

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Explanation

(b) Replacement of N2Cl by halogen atom of CuX-Hfrom benzene diazonium chloride is called Sandmeyer's reaction.

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