NEET Practice Questions (MCQs) with Answers & Solutions

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Which of the following substitution of benzene is ortho-para in electrophilic substitution and ortho-para in nucleophilic substitution ?

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Explanation

(b) -N=O has +M and -M effect depend upon type of group attached.

Many organic compounds are prepared by using PCl5 because:

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Explanation

Substitution of -OH group from a substrate can be easily made by PCl5

Common oxidizing agents used in organic chemistry are;

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Explanation

(d) All these are oxidizing reagents

In E2 elimination, some compounds follow Hofmann's rule which means:

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Explanation

(d) Follow elimination rules.

The hydrolysis of alkyl halides by aqueous NaOH is best termed as:

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Explanation

(d) R-XNaOHR-OH+NaXR-XOH-R-OH+X-this is a nucleophilic substitution reaction

SN1 reaction on optically active substrates mainly gives:

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Explanation

(c) SN1 mechanism gives rise to 50% inversion as it involves front seat as well as back seat substitution. this leads to racemic products

"The negative part of the addendum adds on the carbon atom joined to the least number of hydrogen atoms." This statement is called as:

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Explanation

(a) it is Markownikoff's rule

Hydrolysis of propane gives:

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Explanation

(c) CH3CH2CH3HeterolysisC-H3+CH3C+H2,CH3C+H2  is more stable than CH3-C-H2 due to dispersal of +ve charge on ethylium ion on account of +ve inductive effect.Thus, propane will not give C+H3 and CH3C-H2

Amongst the following which of the above are true for SN2 reaction?

(i) The rate of reaction is independent of the concentration of the nucleophile

(ii) the nucleophile attacks the carbon atom on the side of the molecule opposite to the group being displaced.

(iii) The reaction proceeds with simultaneous bond formation and bond rupture.

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Explanation

(d) Follow characteristics of SN2 mechanism

Carbanions initiate:

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Explanation

Carbanions are nucleophilic species that can initiate both addition and substitution reactions. They can attack electrophilic centers in molecules, leading to addition reactions, or displace leaving groups, resulting in substitution reactions.

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