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For a reaction $ 3A \Psi $ Products, the order of reaction

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Explanation

any value between 1 and 3

The rate determining step in a reaction is $ A + 2B --> C $ . Doubling the concentration of B would make the reaction rate...

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Explanation

$ four times \therefore rate a [B] ^ 2 $

The rate law of a reaction is $ rate = K [A]^ 2[B] $ . On doubling the concentration of both A and B the rate X will become ...

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Explanation

$ 8 x V_1 = k [A]^2 [B] = x V_2 = k [2A]^2 [2B] $ $ \therefore V_2 = 8x $

For the reaction $ CH_3COCH_3 + I_2 + H^+ --> Products $ , the rate is governed by, $ rate = K[CH_3COCH_3] [H^+]$ . The rate order of iodine is = _.

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Explanation

$ OO \therefore No I_2 $ in the rate law equation.

If the order of reaction is zero. It means that

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Explanation

rate of zero order reaction is independent of the concentration of the reacting species

The reactions of higher order are rare because

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Explanation

many body collisions have a low probability

$ 2A +2B ---> D + E $ For the reaction following mechanism has been proposed. $A + 2B --> 2C +D (slow) $ $ A + 2C --> E (Fast) $ The rate law expression for the reaction is

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Explanation

$ rate = K [A][B]^2$ Rate of reaction for slowest step

$ A2 + B2 ---> 2 AB $ reaction follow the mechanism as given below (i) $ A_2 --> 2A (fast) $ (ii) $ A + B_2 --> AB + B (slow) $ (iii) $ A + B ---> AB (fast) $ the order of overall reaction is

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Explanation

$ 1.5 From slowest step rate = k [B_2] [A] $ $ From 1 ^ {st} eq . Keq = [A] { 2 / [ A_2] } $ $ \therefore [A] = keq ^ {1 /2} . [A_2 ] ^ { 1 /2 } $ $ rate = K [B_2] keq ^ {1/2} . [A_2] ^ {1/2} = k .keq ^ {1/2} [A_2] ^ { 1 /2 } [ B_2 ] = K^1 [A_2 ]^ {1 /2 } [B_2 ] $

For the reaction $ 2A + B ---> Products $ , reaction rate = $ K [A][B]^ 2$ . Concentration of A is doubled and that of B is halved the rate of reaction will be ...

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Explanation

$ halved\; rate ' = k [A] [B] ^ 2 rate ' = k [2A] [{B \over 1}] ^ 2 $ $ = { 1 \over 2 } k [A] [B] ^ 2 $ $ \therefore x" = { 1 \over 2 } x ' $

In one reaction concentration of reaction A is increased by 16 times, the rate increases only two times. The order of the reaction would be ...

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Explanation

$ { 1 /4 } ( 1) r = k [A] ^ n (2) 2 r = k [16 A] ^ n $ $ 2r = K [A]^n 16 ^ n $ $ { 2r \over r } = { K [A] ^ n 6 ^ n \over K [A] ^ n } \therefore 2 = 16 ^ n \therefore n = { 1 \over 4} $

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