For a reaction $ 3A \Psi $ Products, the order of reaction
any value between 1 and 3
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For a reaction $ 3A \Psi $ Products, the order of reaction
any value between 1 and 3
The rate determining step in a reaction is $ A + 2B --> C $ . Doubling the concentration of B would make the reaction rate...
$ four times \therefore rate a [B] ^ 2 $
The rate law of a reaction is $ rate = K [A]^ 2[B] $ . On doubling the concentration of both A and B the rate X will become ...
$ 8 x V_1 = k [A]^2 [B] = x V_2 = k [2A]^2 [2B] $ $ \therefore V_2 = 8x $
For the reaction $ CH_3COCH_3 + I_2 + H^+ --> Products $ , the rate is governed by, $ rate = K[CH_3COCH_3] [H^+]$ . The rate order of iodine is = _.
$ OO \therefore No I_2 $ in the rate law equation.
If the order of reaction is zero. It means that
rate of zero order reaction is independent of the concentration of the reacting species
The reactions of higher order are rare because
many body collisions have a low probability
$ 2A +2B ---> D + E $ For the reaction following mechanism has been proposed. $A + 2B --> 2C +D (slow) $ $ A + 2C --> E (Fast) $ The rate law expression for the reaction is
$ rate = K [A][B]^2$ Rate of reaction for slowest step
$ A2 + B2 ---> 2 AB $ reaction follow the mechanism as given below (i) $ A_2 --> 2A (fast) $ (ii) $ A + B_2 --> AB + B (slow) $ (iii) $ A + B ---> AB (fast) $ the order of overall reaction is
$ 1.5 From slowest step rate = k [B_2] [A] $ $ From 1 ^ {st} eq . Keq = [A] { 2 / [ A_2] } $ $ \therefore [A] = keq ^ {1 /2} . [A_2 ] ^ { 1 /2 } $ $ rate = K [B_2] keq ^ {1/2} . [A_2] ^ {1/2} = k .keq ^ {1/2} [A_2] ^ { 1 /2 } [ B_2 ] = K^1 [A_2 ]^ {1 /2 } [B_2 ] $
For the reaction $ 2A + B ---> Products $ , reaction rate = $ K [A][B]^ 2$ . Concentration of A is doubled and that of B is halved the rate of reaction will be ...
$ halved\; rate ' = k [A] [B] ^ 2 rate ' = k [2A] [{B \over 1}] ^ 2 $ $ = { 1 \over 2 } k [A] [B] ^ 2 $ $ \therefore x" = { 1 \over 2 } x ' $
In one reaction concentration of reaction A is increased by 16 times, the rate increases only two times. The order of the reaction would be ...
$ { 1 /4 } ( 1) r = k [A] ^ n (2) 2 r = k [16 A] ^ n $ $ 2r = K [A]^n 16 ^ n $ $ { 2r \over r } = { K [A] ^ n 6 ^ n \over K [A] ^ n } \therefore 2 = 16 ^ n \therefore n = { 1 \over 4} $
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