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At constant temperature, solubility of which of the following substances decreases with increase in temperature ?

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Explanation

The solubility of COâ‚‚ in water decreases with an increase in temperature. This is because the dissolution of COâ‚‚ in water is an exothermic process, and according to Le Chatelier's principle, an increase in temperature shifts the equilibrium towards the endothermic direction, decreasing the solubility.

At constant temperature, in a closed vessel, an ideal solution is formed by liquid – A and liquid – B; and mole-fraction of A and B are 0.6 and 0.4 respectively. If vapour pressure of pure liquids are 125.0 and 62.5 mm respectively, then their mole-fraction in vapour state are respectively – (In vessel, no other component is in gaseous form)

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Explanation

For an ideal solution, the mole fraction of a component in the vapor phase is directly proportional to its vapor pressure. Since the vapor pressures of A and B are 125.0 and 62.5 mm, respectively, their mole fractions in the vapor phase will be in the ratio of 2:1, which corresponds to 0.75 and 0.25.

At constant temperature, two liquids having osmotic pressure $ \nu_1 and \nu_2 $ are seperated by semipermeable membrane, then, what will be the osmotic pressure of the system ?

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Explanation

$ p_A = p^0 _A \times X_A $ $ = 125 \times 0.6 $ = 75 mm $ p_B = p ^ 0_B \times X_B = 62.5 \times 0.4 = 25mm $ $ p_{total} = p_A + p_B = 75 + 25 = 100 mm $ $ p_A = p_{Total} \times Y_A $ $ \therefore 75 = 100 \times Y_A $ $ \therefore Y_A = 0.75 $ $ Similarly \therefore Y_B = 0.25 $

Which of the following pair of solutions forms ideal solution ?

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Explanation

Ideal solutions are formed by mixing two liquids that are chemically similar and have similar intermolecular forces. Benzene and toluene are both non-polar, aromatic hydrocarbons, and their molecules have similar sizes and shapes, allowing them to mix easily, forming an ideal solution.

Which of the following pair forms true solutions ?

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What would be the elevation in boiling point of 0.1 m NaCl solution ? (Assume that Nacl dissociates completely)

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Explanation

$ For NaCl value of i= 2.0 $ $ \therefore \triangle Tb = i.m.Kb = 2 \times 0.1 \times Kb $ $ \therefore \triangle Tb = { Kb \over 5} $

Which of the following semipermeable membrane is best one ?

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Explanation

Cellophane is a semi-permeable membrane made from regenerated cellulose, which allows the passage of small molecules like water but prevents the passage of larger molecules, making it an effective semi-permeable membrane for various applications.

At constant temperature, binary ideal solution is formed by two liquids A and B. At equilibrium, mole-fraction of liquid B is 0.4 and vapour state mole-fraction of B is 0.25. $ P ^\circ B=40 mm$ , then at the same temperature, what will be the vapour pressure of pure liquid ‘A’ ?

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Explanation

$ X_A = 1 -X_B = 1 - 0.4 = 0.6 $ $ Y_A = 1 - Y_B = 1- 0.25 = 0.75 $ $ p_B = p^ \ circ _B \times X_B $ $ \therefore p_B = 40 \times 0.4 $ = 16 mm $ p_B = P_{total} \times Y_B $ $ \therefore 16 = P_{total} \times 0.25 $ $ \therefore P_{total} = 64 mm $ $ p_A = P_{total} \times Y_A = 64 \times 0.75 = 48 mm $ $ Now p_A = p ^ \circ _A \times X_A $ $ 48 = p ^ \circ _A \times 0.6 $ $ \therefre p ^ \circ _A =80 mm $

At constant temperature, 2 litres aqueous solution of each $ 0.2 M kcl and 0.3 M AlCl_3 $ are in contact with each other by semipermeable membrane. When osmosis stops, then, what mililitre water diffuses from semipermeable membrane to the other side ? (Assume that ionic solids dissociates completely in the aqueous solution)

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Explanation

Liquid present in RBC is isotonic with 0.91 % w/v solution of NaCl $ \therefore Morality of soluble particles in 0.91 \% w/v NaCl Solution $ $ = { 2 \times 1000 \times 0.91 \over 58.5 \times 100 } $ $ = 2 \times 0.1555 $ = 0.311 M

Which of the following solution is hypotonic with fluids in RBC ?(Assume that ionic solid substances completely dissociates in the solution)

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Explanation

To determine whether a solution is hypotonic or hypertonic compared to the fluids inside red blood cells (RBCs), we need to consider the concentration of solute particles. The normal osmotic pressure inside RBCs corresponds to a 0.9% NaCl solution, which is approximately 0.154 M NaCl. Therefore, any solution with a lower concentration than 0.154 M NaCl will be hypotonic to RBCs.

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