Atomic Structure MCQs for NEET — Chemistry Questions with Answers

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The  energy needed to convert helium atom  to He +2 is -79eV. The first ionization energy of this atom is about 

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Explanation

(C) He I.EIHe++e-; He+I.EIIHe2++e-

I(I.E)+II(I.E) = 79eV

II(I.E) = 13.6eV x Z2 = 13.6x4eV = 54.4eV

I(I.E) = 79-54.4=24.6eV.

Which of the following has the maximum number of  unpaired electons-

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Explanation

(D) Fe2+ has 1s2,2s22p6,3s23p63d6

configuration with 4 unpaired electron.

Arrange the following particles in increasing order of values of e/m ratio: Electron(e), proton(p), neutron(n) and α-particle(α)

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Explanation

(B)            Electron            Proton            Neutron        α-particle

    e            1 unit               1 unit             zero               2 units

    m          1/1837 unit        1 unit            1 unit            4 unit

   e/m           1837                1                  zero               1/2

Mass of neutron is ........................times the mass of electron-

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Explanation

(A) Mass of neutron = 1.675 x 10-27kg

Mass of electron = 9.108 x 10-31 kg.

If the size of the first orbit of hydrogen atom is 5.29 nm, the size of the second orbit of He+ is

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Explanation

(B) Size of the first orbit of Hydrogen = 5.29 x 10-9m

Size of the second orbit of Helium = 5.29 x 10-9 x 22 /2= 10.58 nm.

The number of d- electrons retained in Fe2+ :

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Explanation

(b) Fe is 3d6, 4s2; Fe2+: 3d6

What transition in the hydrogen spectrum would have the same wavelength as the Balmer transition, n=4 to n=2 in the He+ spectrum?

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Which of the following sets of quantum numbers is not possible?

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Explanation

if n = 3 then l=3 is not possible.

An isotone of 32Ge76 is:

(i) 32Ge77 

(ii) 33As77 

(iii) 34Se77 

(iv) 34Se78 

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Explanation

Isotones are these in which number of neutrons are same.

Which of the following species has more number of electrons in comparison with the neutrons?

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Explanation

In O2- , number of electrons are 10 and number of neutrons are 8

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