Atomic Structure MCQs for NEET — Chemistry Questions with Answers

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The threshold frequency ($\nu_0$) for photoelectric emission is defined as the:

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Explanation

The text defines it as: 'This minimum, cut-off frequency $\nu_0$, is called the threshold frequency. It is different for different metals.' And 'Below a certain frequency (threshold frequency) $\nu_0$, characteristic of the metal, no photoelectric emission takes place, no matter how large the intensity may be.'

What is the approximate time lag observed between the incidence of light and the emission of photoelectrons, provided the frequency is above the threshold frequency?

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Explanation

The text explicitly states: 'It is now known that emission starts in a time of the order of $10^{-9}$ s or less.' This indicates the instantaneous nature of the process.

Which of the following metals is stated to be sensitive to visible light for photoelectric emission?

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Explanation

The text mentions: 'However, some alkali metals such as lithium, sodium, potassium, caesium and rubidium were sensitive even to visible light.' Zinc and cadmium are mentioned as responding to ultraviolet light.

According to Einstein's photoelectric equation, the maximum kinetic energy of photoelectrons ($K_{max}$) is given by:

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Explanation

Einstein’s photoelectric equation is given as: '$1/2 m v^2_{max} = V_0 e = h\nu – \phi_0 = h (\nu – \nu_0)$'. Here, $\phi_0$ represents the work function, which is $h\nu_0$.

The stopping potential ($V_0$) depends on:

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Explanation

Point 4 in the summary states: 'The stopping potential ($V_0$) depends on (i) the frequency of incident light, and (ii) the nature of the emitter material. For a given frequency of incident light, it is independent of its intensity.'

When the frequency of incident light on a photosensitive material is increased, what happens to the stopping potential, assuming intensity is kept constant?

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Explanation

Figure 11.4 and its description state: 'The stopping potential is more negative for higher frequencies of incident radiation.' This implies that as frequency increases, the stopping potential increases in magnitude (becomes more negative). This is also consistent with $V_0 = (h/e)(\nu - \nu_0)$, where $h/e$ is positive.

What is the primary reason why classical wave theory failed to explain the photoelectric effect?

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Explanation

Point 6 in the summary states: 'The classical wave theory could not explain the main features of photoelectric effect. Its picture of continuous absorption of energy from radiation could not explain the independence of $K_{max}$ on intensity, the existence of $\nu_0$ and the instantaneous nature of the process.' All listed options are correct reasons for its failure.

In the experimental setup for studying the photoelectric effect, what is the role of the commutator?

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Explanation

The text describes the setup: 'The polarity of the plates C and A can be reversed by a commutator. Thus, the plate A can be maintained at a desired positive or negative potential with respect to emitter C.'

What happens to the saturation current if the intensity of incident radiation is increased, while keeping the frequency constant (above threshold)?

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Explanation

Figure 11.3 demonstrates this: 'We note that the saturation currents are now found to be at higher values' when intensity is increased (I3 > I2 > I1 corresponds to higher saturation currents). The photoelectric current is directly proportional to the number of photoelectrons emitted per second, which in turn is proportional to the intensity.

The photoelectric effect involves the conversion of:

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Explanation

The text clearly states: 'Photoelectric effect involves conversion of light energy into electrical energy.'

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