Chemical Thermodynamics MCQs for NEET — Chemistry Questions with Answers

Choose the correct option about the following sentnences [T= True , F =False]

(i) Ice in contact with water constitutes a homogeneous system.

(ii) The process is known as isochoric in which the pressure remains constant throughout the change, i.e., dP = 0.

(iii) A spontaneous process is reversible in nature.

(iv) In an isolated system, one form of energy cannot be converted into another, i.e., internal energy remains constant.

Choose the correct option about the following sentnences [T= True , F =False] (i)Molar heat capacity at constant pressure = Molar heat capacity at constant volume + POV. (ii)A spontaneous process is accompanied by a decrease in entropy. (iii) $ \triangle Hsub = \triangle Hfusion + \triangle Hvap $ . (iv)The standard heat of formation represents the formation of the compound from its elements at $ 25 ^\circ C $ and one atmospheric pressure. (v)Whenever an acid is neutralised by a base, the net reaction is

Match the following Column–I A. Isothermal process B. Adiabatic process C. Isobaric process D. Isochoric process Column–II P. $ q = \triangle U $ Q. $ w = – P \triangle V $ R. $ w = \triangle U $ S. $ w = –n RT ln (V_2/V_1) $

Reasoning question choose the correct statement. Statement–1 : The enthalpy of formation of $H_2O(l)$ is greater than of $H_2O (g) $ . Statement–2: Enthalpy change is negative for the condensation reaction $H_2O (g) \rightarrow H_2O(l) $

Reasoning question choose the correct statement. Statement–1 : Heat of neutralisation of perchloric acid, $HClO_3$, with NaOH is same as that of HCl with NaOH. Statement–2: Both HCl and $HClO_4$ are strong acids.

Reasoning question choose the correct statement. Statement–1 : When a gas at high pressure expands against vacuum, the work done is maximum. Statement–2: Work done in expansion depends upon the pressure inside the gas and increase in volume.

Reasoning question choose the correct statement. Statement I : The chemical reaction, $3H_2(g) + N_2(g) \rightarrow 2NH_3 $ shows decrease in entropy. Statement II: The process passes into equilibrium state when $ \triangle GT,P $ becomes zero.

Calculate the work performed when 2 moles of hydrogen expand isothermally and reversibly at $25 ^\circ C $ form 15 to 50 litres.

The $ \triangle H_f0 for CO_2(g), CO(g) and H_2O (g)$ are –393.5, –110.5 and –241.8 $kJ mol^{–1} $ respectively. The standard enthalpy change (in kJ) for the reaction $CO_2(g) + H_2(g) \rightarrow CO(g) + H_2O (g) $ is –

For reaction carried out in automobiles, what is the value of $ \triangle H , \triangle S and \triangle G ? $ $ 2C_8H_{18} (g) + 25O_2(g) 16CO_2(g)+ 18H_2O(g) $