Chemical Thermodynamics MCQs for NEET — Chemistry Questions with Answers

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If ΔH is the change in enthalpy and ΔE the change in internal energy accompanying a gaseous reaction [KCET 1989; CBSE PMT 1990]

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Explanation

If Δn = –ve than ΔH < ΔE.

Enthalpy for the reaction C + O2 → CO2 is [DPMT 1987, 91]

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Explanation

It is a combustion reaction, ΔH = –ve.

The work done in ergs for the reversible expansion of one mole of an ideal gas from a volume of 10 litres to 20 litres at 25°C is 

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Explanation

W=2.303  nRTlogV2V1

=2.303  ×1  ×8.314  ×107×298log2010

=298  ×107×8.314  ×2.303  log  2.

In a reversible isothermal process, the change in internal energy is

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Explanation

ΔE = 0 for reversible isothermal process.

The enthalpy of neutralization of which of the following acids and bases is nearly –13.6 Kcal [Roorkee 1999]

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Explanation

Heat of neutralisation of a strong acid and strong base is equal to –13.7 kcal.

Work done during isothermal expansion of one mole of an ideal gas from 10 atm to 1 atm at 300 K is (Gas constant = 2) [AIIMS 2000]

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Explanation

W=+2.303nRT log p1p2

W=2.303×1×2×300 log 101=1381.8cal. 

Joule-Thomson expansion is [JIPMER 2000]

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Explanation

Joule-Thomson expansion is isoenthalpic.

thermodynamics, the Joule–Thomson effect (also known as the Joule–Kelvin effectKelvin–Joule effect) describes the temperature change of a real gas or liquid (as differentiated from an ideal gas) when it is forced through a valve or porous plug while keeping it insulated so that no heat is exchanged with the environment.[1][2][3]This procedure is called a throttling process or Joule–Thomson process.[4] At room temperature, all gases except hydrogenhelium and neon cool upon expansion by the Joule–Thomson process when being throttled through an orifice; these three gases experience the same effect but only at lower temperatures.[5][6] Most liquids such as hydraulic oils will be warmed by the Joule-Thomson throttling process.

The gas-cooling throttling process is commonly exploited in refrigeration processes such as air conditioners, heat pumps, and liquefiers.[7][8] In hydraulics, the warming effect from Joule-Thomson throttling can be used to find internally leaking valves as these will produce heat which can be detected by thermocouple or thermal-imaging camera. Throttling is a fundamentally irreversible process. The throttling due to the flow resistance in supply lines, heat exchangers, regenerators, and other components of (thermal) machines is a source of losses that limits the performance.

In an adiabatic expansion of an ideal gas [KCET (Med.) 2001; MH CET 2000]

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Explanation

q = ΔE – W, if q = 0 for adiabatic process, than ΔE = W.

For the reaction CH3COOH(l)+2O2(g)2CO2(g)+2H2O(l) at 25°C and 1 atm. pressure, ΔH = –874 kJ. Then the change in internal energy (ΔE) is …. [Orissa JEE 2002]

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Explanation

For this reaction Δn = 0 than ΔE = ΔH.

One mole of an ideal gas is allowed to expand freely and adiabatically into vacuum until its volume has doubled. A statement which is not true concerning this expression is [Pb. PMT 1998]

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Explanation

ΔS = 0 is not true.

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