Equilibrium MCQs for NEET — Chemistry Questions with Answers

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N2O4 dissociates as N2O4(g)2NO2(g) at 273 K and 2 atm pressure. The equilibrium mixture has a vapour density of 41. What will be the percentage degree of dissociation ?

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Explanation

Use, 

α=D-d(n-1)d

D=Theorotical vapour dessity

d= Observed apour density

n= No. of moles obtained after dissociation after one mole

α=46-41(2-1)41=0.122

% dissociation = 12.2%

On the adding inert gas to the equilibrium PCl5(g)PCl3(g) + Cl2(g) at constant pressure. The degree of dissociation will :

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Explanation

On adding inert gas at constant pressure, equilibrium shifts in tht direction where the number of moles are more.

The stability product constant Ksp of Mg(OH)2 is 9.0 X 10-12. If a solution is 0.010 M with respect to Mg2+ ion, waht is the maximum hydroxide ion concentration which could be present without causing the precipitation of Mg(OH)2

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Explanation

Mg(OH)2Mg2+ + 2OH-Ksp=[Mg2+] [OH-]29 × 10-12=0.01 × [OH-]2[OH-] =3 ×10-5M

Which may be added to one litre of water to act as a buffer

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Explanation

 

CH3COOH + NaOH CH3COONa + H2O

At t=0          1        0.5          0        0

Att t='t'       0.5        0         0.5      0.5

Now it is the acidic buffer solution.

Acoording to Bronsted-Lowry concept, the correct order of relative strength of bases follows the order

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Explanation

All weak acid has strong conjugate base and strong acid has weak conjugate base.

pOH of H2O is 7.0 at 298K. If water is heated at 350K, which of the following statement should be true ?

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Explanation

On heating dissociationof H2O increases. SO, [H+] as well s [OH-] increases and pH as well as pOH decreases.

In which case following equilibrium can't be established:

CaCO3(s) CaO(s) + CO2(g)

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Explanation

When pressure of CO2 gas greater than Kp then it can't shift in backward direction without CaO.

Solubility product constant (Ksp) of salts of types MX,MX2 and M3X at temperature T are 4.0 X 10-8, 3.2 X 10-14 and 2.7 X 10-15 respectively. Solublities(mol dm-3) of the salts at temperature T are the order:

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Explanation

For Mx, Ksp =S2

     For MX2, Ksp =4S3

     For M3X, Ksp =27S 4

Use the above formula and calculate the solubilities.

At 25°C the specific conductance of sturated solution of AgCl is 2.3 X 10-6 ohm-1cm-1. What will be the solubility of AgCl at 25°C if iconic conductances of Ag and Cl at infinite dilution are 61.9 and 76.3 ohm-1cm2mol-1 respectively.

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Explanation

 

 

 Solubility (S)=K×1000Λm                       =2.3×10-6×100061.9 + 76.3                       =2.3×10-3138.2                       =1.66 × 10-5mol/L

In the reaction, N2O4  2NO2α is that part of N2O4 which dissociates, then the number of moles at equilibrium will be:

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Explanation

4. N2O4 2NO2

       1         0     ---- at zero times

     1-α       2α   ---- at equilibrium

 No. of moles at equilibrium = 1-α+2α= 1+α

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