Some Basic Concepts in Chemistry MCQs for NEET — Chemistry Questions with Answers

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Which of the following pairs of gases contains the same number of molecules:-

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Explanation

Mole (n) = Weight Molecular weight=No. of moleculesNA

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The number of ions present in 2L of a solution of 1.6M K4[Fe(CN)6] is:-

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Explanation

No. of molecules of  K4[Fe(CN)6] = 1.6 x 2 x 6 x 1023

No. of ions = 5 x 1.6 x 2 x 6 x 1023

= 9.6 x 1024

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The mass of CO2 that shall be obtained by heating 10 kg of 80% pure lime stone (CaCO3) is:-

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Explanation

CaCO3(S) →∆ CO2(g) + CaO(s)

100 kg →44 kg

80100×10kg →44100×80100×10=3.52 kg

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When 1L of CO2 is heated with graphite,the volume of the gases collected is 1.8L. What will be the number of moles of CO produced at STP?

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Explanation

The reaction is: C(s) + CO2(g) → 2CO(g). Initially, there are 1 mol of CO2. After the reaction, the total volume is 1.8 L, which corresponds to 1.8 mol of gaseous product (assuming STP). Since 1 mol of CO2 produces 2 mol of CO, the moles of CO produced is 0.0714 mol.

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At STP the moles of oxygen atoms in 2.8 L of CO2 gas is:-

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Explanation

Moles of CO2 = volume of gas22.4=2.822.4=0.125 mol

moles of oxygen atom in given CO2 = 0.125 x 2=0.25 mol

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Which of the following relation is incorrect:-

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Explanation

1 mol N-3 ion →1 x 10 mol e- 

1 mol O-2 ion →1 x 10 mol e- = 6.023x10-24e-

1 mol CH4 →1 x 10 mol proton

1 mol H2O →1 x 10 mol proton

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Mass of sucrose C12H22O11 produced by mixing 84 gm of carbon, 12gm of hydrogen and 56L. O2 at 1atm & 273 K according to give reaction, is C(s) + H2(g) +O2(g) → C12H22O11 (s)

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Explanation

Balanced Equation:

24C + 22H2 + 11O2 -> 2C12H22O11

moles for reaction: 

7(84/12), 6(12/2), (56/22.4)

dividing by coefficients in balanced equation & comparing: 

7/24, 6/22,  (56/22.4)/11 

0.29, 0.27, 0.22

Oxygen is the limiting reagent. So, weight of sucrose obtained = 0.22 * 2(coefficient for sucrose in reaction) * 342(sucrose molecular weight) = 155.5g

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A mixture contains Na2CO3 and NaHCO3 and wt. of mixture is 10gm. Mixture on heating liberates 56ml of CO2 at S.T.P, wt of Na2CO3 in mixture is

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Explanation

Only NaHCO3 evolve CO2 gas. Na2CO3 does not evolve CO2 gas even on red heating.

So, the only reaction happening is: 

2NaHCO3 -> Na2CO3 + CO2 + H2O

Weight: 

2(23+1+12+16*3) -> (2*23+12+16*3) + (12+16*2) +  (1*2+16)
                               
    168g                 ->         102g          +       44g      +    18g

Also, CO2 mass as per 56ml volume obtained at STP = 56/(22.4 * 1000) * (44) = 0.11g

So, NaHCO3 weight = 0.11/44*168 = 0.42g (using ratio of weights from equation)

Therefore, original Na2CO3 weight in the original mixture = 10 - 0.42 = 9.58g

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How many moles of KMnO4 are needed a mixture of 1 mole of each FeSO4 & FeC2O4 in acidic medium

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Explanation

Equivalents of KMnO4 = equivalent of FeSO4 + equivalent of FeC2O4

x × 5=1 × 1 + 1 × 3

x = 45 mole

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The percentage of copper in a copper(II) salt can be determined by using a thiosulphate titration. 0.305 gm of a copper(II) salt was dissolved in water and added to, an excess of potassium iodide solution liberating iodine according to the following equation 2Cu2 (aq) + 4I– (aq) ⇌ 2CuI(s) + I2(aq) The iodine liberated required 24.5cm3 of a 0.100 mole dm-3 solution of sodium thiosulphate 2S2O32- (aq) + I2(aq) → 2I– (aq) + S4O62- (aq) the percentage of copper, by mass in the copper(ll) salt is. [Atomic mass of copper = 63.5]

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Explanation

From given reactions

mmoles of hypo = mmoles of iodine × 2

= mmoles of Cu2+ ions

= 24.5 × 0.1 mmoles

So mass of copper = 24.5 × 0.1 × 10–3 × 63.5 gm

So % of copper = 24.5 × 0.1 × 10−3 × 63.50.305 × 100% ≃ 51.0 %

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